Limits...
[2-(2-Carboxy-phen-yl)benzoato]bis-(1,10-phenanthroline)zinc(II) 2-(2-carboxy-phen-yl)benzoate monohydrate.

Huang WW, Yang SP - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The phenanthroline and carboxylate ligands act as chelating ligands.The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion).O-H⋯O and C-H⋯O hydrogen bonds link the components into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry, Shanghai Normal University, Shanghai 200234, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octa-hedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxyl-ate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion). O-H⋯O and C-H⋯O hydrogen bonds link the components into a three-dimensional network.

No MeSH data available.


The crystal packing of the title compound, viewed down the a axis. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2961034&req=5

Fap2: The crystal packing of the title compound, viewed down the a axis. Hydrogen bonds are shown as dashed lines.


[2-(2-Carboxy-phen-yl)benzoato]bis-(1,10-phenanthroline)zinc(II) 2-(2-carboxy-phen-yl)benzoate monohydrate.

Huang WW, Yang SP - Acta Crystallogr Sect E Struct Rep Online (2008)

The crystal packing of the title compound, viewed down the a axis. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961034&req=5

Fap2: The crystal packing of the title compound, viewed down the a axis. Hydrogen bonds are shown as dashed lines.
Bottom Line: The phenanthroline and carboxylate ligands act as chelating ligands.The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion).O-H⋯O and C-H⋯O hydrogen bonds link the components into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry, Shanghai Normal University, Shanghai 200234, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octa-hedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxyl-ate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion). O-H⋯O and C-H⋯O hydrogen bonds link the components into a three-dimensional network.

No MeSH data available.