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Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]zinc(II).

Fun HK, Chantrapromma S, Tarafder MT, Islam MT, Zakaria CM, Islam MA - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands.The dihedral angle between each ligand is 71.48 (8)°.Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis.

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ABSTRACT
In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-H⋯π inter-actions involving the phenyl ring of the 3-phenyl-prop-2-enyl-idene unit.

No MeSH data available.


Related in: MedlinePlus

The asymmetric unit of the title compound, showing 50% probability displacement ellipsoids and the atomic numbering. Atoms labelled with suffix A are generated by the symmetry operation (-x, y, 1/2 - z).
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Fap1: The asymmetric unit of the title compound, showing 50% probability displacement ellipsoids and the atomic numbering. Atoms labelled with suffix A are generated by the symmetry operation (-x, y, 1/2 - z).


Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]zinc(II).

Fun HK, Chantrapromma S, Tarafder MT, Islam MT, Zakaria CM, Islam MA - Acta Crystallogr Sect E Struct Rep Online (2008)

The asymmetric unit of the title compound, showing 50% probability displacement ellipsoids and the atomic numbering. Atoms labelled with suffix A are generated by the symmetry operation (-x, y, 1/2 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961027&req=5

Fap1: The asymmetric unit of the title compound, showing 50% probability displacement ellipsoids and the atomic numbering. Atoms labelled with suffix A are generated by the symmetry operation (-x, y, 1/2 - z).
Bottom Line: It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands.The dihedral angle between each ligand is 71.48 (8)°.Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-H⋯π inter-actions involving the phenyl ring of the 3-phenyl-prop-2-enyl-idene unit.

No MeSH data available.


Related in: MedlinePlus