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2-Methyl-1-(phenyl-sulfon-yl)naphtho[2,1-b]furan.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, C(19)H(14)O(3)S, was prepared by the oxidation of 2-methyl-1-(phenyl-sulfan-yl)naphtho[2,1-b]furan with 3-chloro-peroxy-benzoic acid.The phenyl ring makes a dihedral angle of 87.13 (4)° with the plane of the naphthofuran fragment.In addition, there are also intra-molecular C-H⋯O inter-actions.

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ABSTRACT
The title compound, C(19)H(14)O(3)S, was prepared by the oxidation of 2-methyl-1-(phenyl-sulfan-yl)naphtho[2,1-b]furan with 3-chloro-peroxy-benzoic acid. The phenyl ring makes a dihedral angle of 87.13 (4)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by π-π inter-actions between the furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.850 (2) Å] and weak C-H⋯π inter-actions. In addition, there are also intra-molecular C-H⋯O inter-actions.

No MeSH data available.


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π—π, C—H···π and intramolecular C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroids. [Symmetry code: (i) 1 - x, -y, -z; (ii) 2 - x, 1 - y, -z; (iii) x + 1, y + 1, z.]
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Fap2: π—π, C—H···π and intramolecular C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroids. [Symmetry code: (i) 1 - x, -y, -z; (ii) 2 - x, 1 - y, -z; (iii) x + 1, y + 1, z.]


2-Methyl-1-(phenyl-sulfon-yl)naphtho[2,1-b]furan.

Choi HD, Seo PJ, Son BW, Lee U - Acta Crystallogr Sect E Struct Rep Online (2008)

π—π, C—H···π and intramolecular C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroids. [Symmetry code: (i) 1 - x, -y, -z; (ii) 2 - x, 1 - y, -z; (iii) x + 1, y + 1, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961025&req=5

Fap2: π—π, C—H···π and intramolecular C—H···O interactions (dotted lines) in the title compound. Cg denotes the ring centroids. [Symmetry code: (i) 1 - x, -y, -z; (ii) 2 - x, 1 - y, -z; (iii) x + 1, y + 1, z.]
Bottom Line: The title compound, C(19)H(14)O(3)S, was prepared by the oxidation of 2-methyl-1-(phenyl-sulfan-yl)naphtho[2,1-b]furan with 3-chloro-peroxy-benzoic acid.The phenyl ring makes a dihedral angle of 87.13 (4)° with the plane of the naphthofuran fragment.In addition, there are also intra-molecular C-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(19)H(14)O(3)S, was prepared by the oxidation of 2-methyl-1-(phenyl-sulfan-yl)naphtho[2,1-b]furan with 3-chloro-peroxy-benzoic acid. The phenyl ring makes a dihedral angle of 87.13 (4)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by π-π inter-actions between the furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.850 (2) Å] and weak C-H⋯π inter-actions. In addition, there are also intra-molecular C-H⋯O inter-actions.

No MeSH data available.


Related in: MedlinePlus