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3-Methyl-N-phen-ylbenzamide.

Gowda BT, Foro S, Sowmya BP, Fuess H - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The amide group -NHCO- forms dihedral angles of 20.97 (34) and 45.65 (19)° with the benzoyl rings, and 41.54 (25) and 31.87 (29)° with the aniline rings, in the two independent mol-ecules.The benzoyl and aniline rings adopt dihedral angles of 22.17 (18) and 75.86 (12)° in the two independent mol-ecules.In the crystal structure, mol-ecules are linked into chains by inter-molecular N-H⋯O hydrogen bonds.

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ABSTRACT
The conformation of the C=O bond in the structure of the title compound, C(14)H(13)NO, is anti to the meta-methyl substituent in the benzoyl ring. The conformations of the N-H and C=O bonds in the amide group are also anti to each other. The asymmetric unit of the structure contains two mol-ecules. The bond parameters are similar to those in N-(phen-yl)benzamide, 2-methyl-N-(phenyl)-benz-amide and other benzanilides. The amide group -NHCO- forms dihedral angles of 20.97 (34) and 45.65 (19)° with the benzoyl rings, and 41.54 (25) and 31.87 (29)° with the aniline rings, in the two independent mol-ecules. The benzoyl and aniline rings adopt dihedral angles of 22.17 (18) and 75.86 (12)° in the two independent mol-ecules. In the crystal structure, mol-ecules are linked into chains by inter-molecular N-H⋯O hydrogen bonds.

No MeSH data available.


Molecular structure of the title compound, showing the atom labeling scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are represented as small spheres of arbitrary radii.
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Fap1: Molecular structure of the title compound, showing the atom labeling scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are represented as small spheres of arbitrary radii.


3-Methyl-N-phen-ylbenzamide.

Gowda BT, Foro S, Sowmya BP, Fuess H - Acta Crystallogr Sect E Struct Rep Online (2008)

Molecular structure of the title compound, showing the atom labeling scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are represented as small spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2961009&req=5

Fap1: Molecular structure of the title compound, showing the atom labeling scheme. The displacement ellipsoids are drawn at the 50% probability level. H atoms are represented as small spheres of arbitrary radii.
Bottom Line: The amide group -NHCO- forms dihedral angles of 20.97 (34) and 45.65 (19)° with the benzoyl rings, and 41.54 (25) and 31.87 (29)° with the aniline rings, in the two independent mol-ecules.The benzoyl and aniline rings adopt dihedral angles of 22.17 (18) and 75.86 (12)° in the two independent mol-ecules.In the crystal structure, mol-ecules are linked into chains by inter-molecular N-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The conformation of the C=O bond in the structure of the title compound, C(14)H(13)NO, is anti to the meta-methyl substituent in the benzoyl ring. The conformations of the N-H and C=O bonds in the amide group are also anti to each other. The asymmetric unit of the structure contains two mol-ecules. The bond parameters are similar to those in N-(phen-yl)benzamide, 2-methyl-N-(phenyl)-benz-amide and other benzanilides. The amide group -NHCO- forms dihedral angles of 20.97 (34) and 45.65 (19)° with the benzoyl rings, and 41.54 (25) and 31.87 (29)° with the aniline rings, in the two independent mol-ecules. The benzoyl and aniline rings adopt dihedral angles of 22.17 (18) and 75.86 (12)° in the two independent mol-ecules. In the crystal structure, mol-ecules are linked into chains by inter-molecular N-H⋯O hydrogen bonds.

No MeSH data available.