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(1R,2R)-N,N'-Dimethyl-cyclo-hexane-1,2-diamine.

Strohmann C, Gessner VH, Damme A, Koller S, Däschlein C - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The cyclo-hexane ring shows a chair conformation with the amino groups in equatorial positions.Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature (293 K).The absolute configuration is assigned from the synthesis.

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Affiliation: Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

ABSTRACT
The molecule of the title compound, C(8)H(18)N(2), possesses C(2) symmetry. Owing to its stereochemistry, it is used in the synthesis of chiral ligands and metal complexes for asymmetric synthesis. The cyclo-hexane ring shows a chair conformation with the amino groups in equatorial positions. Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature (293 K). The absolute configuration is assigned from the synthesis.

No MeSH data available.


Display of the hydrogen bonding.
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Fap3: Display of the hydrogen bonding.


(1R,2R)-N,N'-Dimethyl-cyclo-hexane-1,2-diamine.

Strohmann C, Gessner VH, Damme A, Koller S, Däschlein C - Acta Crystallogr Sect E Struct Rep Online (2008)

Display of the hydrogen bonding.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960996&req=5

Fap3: Display of the hydrogen bonding.
Bottom Line: The cyclo-hexane ring shows a chair conformation with the amino groups in equatorial positions.Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature (293 K).The absolute configuration is assigned from the synthesis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.

ABSTRACT
The molecule of the title compound, C(8)H(18)N(2), possesses C(2) symmetry. Owing to its stereochemistry, it is used in the synthesis of chiral ligands and metal complexes for asymmetric synthesis. The cyclo-hexane ring shows a chair conformation with the amino groups in equatorial positions. Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature (293 K). The absolute configuration is assigned from the synthesis.

No MeSH data available.