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Di-μ-chlorido-bis-[bis-(η-cyclo-octene)iridium(I)].

Yamagata T, Nakajima K, Arimitsu K, Iseki A, Tani K - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å.Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.

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ABSTRACT
The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.

No MeSH data available.


The molecular structure, showing the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level. All H atoms are omitted. Ca, Cb, Cc and Cd are the centroids of the coordinated C?C bonds.
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Fap1: The molecular structure, showing the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level. All H atoms are omitted. Ca, Cb, Cc and Cd are the centroids of the coordinated C?C bonds.


Di-μ-chlorido-bis-[bis-(η-cyclo-octene)iridium(I)].

Yamagata T, Nakajima K, Arimitsu K, Iseki A, Tani K - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure, showing the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level. All H atoms are omitted. Ca, Cb, Cc and Cd are the centroids of the coordinated C?C bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960958&req=5

Fap1: The molecular structure, showing the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level. All H atoms are omitted. Ca, Cb, Cc and Cd are the centroids of the coordinated C?C bonds.
Bottom Line: The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å.Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.

No MeSH data available.