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2-Thienylcarbonylmethylene-triphenylphosphorane ylide.

Sabounchei SJ, Jodaian V, Khavasi HR - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the mol-ecule of the title compound, (2-thienylcarbon-yl)(triphenyl-phospho-nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra-hedral and the O-C-C-P torsion angle is 2.80 (3)°.The thio-phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the carbonyl group.Inter- and intra-molecular hydrogen bonds and C-H⋯π inter-actions are present in the crystal structure.

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ABSTRACT
In the mol-ecule of the title compound, (2-thienylcarbon-yl)(triphenyl-phospho-nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra-hedral and the O-C-C-P torsion angle is 2.80 (3)°. The thio-phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the carbonyl group. Inter- and intra-molecular hydrogen bonds and C-H⋯π inter-actions are present in the crystal structure.

No MeSH data available.


Related in: MedlinePlus

The molecular structure with the atom-numbering scheme. Displacement ellipsoids are drawn at 30% probability level.
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Fap1: The molecular structure with the atom-numbering scheme. Displacement ellipsoids are drawn at 30% probability level.


2-Thienylcarbonylmethylene-triphenylphosphorane ylide.

Sabounchei SJ, Jodaian V, Khavasi HR - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure with the atom-numbering scheme. Displacement ellipsoids are drawn at 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960945&req=5

Fap1: The molecular structure with the atom-numbering scheme. Displacement ellipsoids are drawn at 30% probability level.
Bottom Line: In the mol-ecule of the title compound, (2-thienylcarbon-yl)(triphenyl-phospho-nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra-hedral and the O-C-C-P torsion angle is 2.80 (3)°.The thio-phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the carbonyl group.Inter- and intra-molecular hydrogen bonds and C-H⋯π inter-actions are present in the crystal structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the mol-ecule of the title compound, (2-thienylcarbon-yl)(triphenyl-phospho-nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra-hedral and the O-C-C-P torsion angle is 2.80 (3)°. The thio-phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the carbonyl group. Inter- and intra-molecular hydrogen bonds and C-H⋯π inter-actions are present in the crystal structure.

No MeSH data available.


Related in: MedlinePlus