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Dioxidobis(2-oxo-1,2-dihydropyridin-3-olato)-molybdenum(VI).

Trivedi M, Pandey DS, Rath NP - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Mo(C(5)H(4)NO(2))(2)O(2)], the Mo(VI) atom exhibits a distorted octa-hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands.The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other.The crystal structure contains inter-molecular N-H⋯O hydrogen bonds, C-H⋯O contacts and face-to-face π-π stacking inter-actions with an inter-planar separation of 3.25 (1) Å.

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ABSTRACT
In the title compound, [Mo(C(5)H(4)NO(2))(2)O(2)], the Mo(VI) atom exhibits a distorted octa-hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains inter-molecular N-H⋯O hydrogen bonds, C-H⋯O contacts and face-to-face π-π stacking inter-actions with an inter-planar separation of 3.25 (1) Å.

No MeSH data available.


Related in: MedlinePlus

The molecular structure with displacement ellipsoids drawn at the 50% probability level for non-H atoms
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Fap1: The molecular structure with displacement ellipsoids drawn at the 50% probability level for non-H atoms


Dioxidobis(2-oxo-1,2-dihydropyridin-3-olato)-molybdenum(VI).

Trivedi M, Pandey DS, Rath NP - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure with displacement ellipsoids drawn at the 50% probability level for non-H atoms
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960932&req=5

Fap1: The molecular structure with displacement ellipsoids drawn at the 50% probability level for non-H atoms
Bottom Line: In the title compound, [Mo(C(5)H(4)NO(2))(2)O(2)], the Mo(VI) atom exhibits a distorted octa-hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands.The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other.The crystal structure contains inter-molecular N-H⋯O hydrogen bonds, C-H⋯O contacts and face-to-face π-π stacking inter-actions with an inter-planar separation of 3.25 (1) Å.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Mo(C(5)H(4)NO(2))(2)O(2)], the Mo(VI) atom exhibits a distorted octa-hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains inter-molecular N-H⋯O hydrogen bonds, C-H⋯O contacts and face-to-face π-π stacking inter-actions with an inter-planar separation of 3.25 (1) Å.

No MeSH data available.


Related in: MedlinePlus