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4-[(E)-2-Ferrocenylethen-yl]-1,8-naphthalic anhydride.

Munro NH, Hanton LR, McAdam CJ, McMorran DA - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system.In the crystal structure, centrosymmetric dimers are formed through π-π inter-actions [centroid-centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit.Pairs of dimers are held together by further naphthalene-naphthalene π-π interactions [distance between parallel mean planes 3.45 (3) Å].

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Affiliation: Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.

ABSTRACT
In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π-π inter-actions [centroid-centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit. Pairs of dimers are held together by further naphthalene-naphthalene π-π interactions [distance between parallel mean planes 3.45 (3) Å]. Each dimer inter-acts with four neighbouring dimers in a herringbone fashion through C-H⋯π inter-actions, so forming a two-dimensional sheet-like structure.

No MeSH data available.


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The molecular structure of compound I, showing the atom numbering scheme and displacement ellipsoids drawn at the 50% probability level.
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Fap1: The molecular structure of compound I, showing the atom numbering scheme and displacement ellipsoids drawn at the 50% probability level.


4-[(E)-2-Ferrocenylethen-yl]-1,8-naphthalic anhydride.

Munro NH, Hanton LR, McAdam CJ, McMorran DA - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of compound I, showing the atom numbering scheme and displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960931&req=5

Fap1: The molecular structure of compound I, showing the atom numbering scheme and displacement ellipsoids drawn at the 50% probability level.
Bottom Line: In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system.In the crystal structure, centrosymmetric dimers are formed through π-π inter-actions [centroid-centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit.Pairs of dimers are held together by further naphthalene-naphthalene π-π interactions [distance between parallel mean planes 3.45 (3) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.

ABSTRACT
In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π-π inter-actions [centroid-centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit. Pairs of dimers are held together by further naphthalene-naphthalene π-π interactions [distance between parallel mean planes 3.45 (3) Å]. Each dimer inter-acts with four neighbouring dimers in a herringbone fashion through C-H⋯π inter-actions, so forming a two-dimensional sheet-like structure.

No MeSH data available.


Related in: MedlinePlus