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Chlorido{2-[1-(2-pyridylmethyl-imino)eth-yl]pyrrolato-κN,N',N''}copper(II).

Li R, Zhao P, Tang G, Tao Y - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The potential tridentate Schiff base ligand 2-[1-(2-pyridyl-methyl-imino)eth-yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl-pyrrole with 2-amino-methyl-pyridine.The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl-amine as a base to deprotonate the pyrrole NH group.The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.

View Article: PubMed Central - HTML - PubMed

Affiliation: Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Teachers College, Huai'an 223300, Jiangsu Province, People's Republic of China.

ABSTRACT
The potential tridentate Schiff base ligand 2-[1-(2-pyridyl-methyl-imino)eth-yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl-pyrrole with 2-amino-methyl-pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl-amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.

No MeSH data available.


Related in: MedlinePlus

View of the crystal packing along b axis of the unit cell of the monomeric title complex [CuLCl].
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Fap2: View of the crystal packing along b axis of the unit cell of the monomeric title complex [CuLCl].


Chlorido{2-[1-(2-pyridylmethyl-imino)eth-yl]pyrrolato-κN,N',N''}copper(II).

Li R, Zhao P, Tang G, Tao Y - Acta Crystallogr Sect E Struct Rep Online (2008)

View of the crystal packing along b axis of the unit cell of the monomeric title complex [CuLCl].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960930&req=5

Fap2: View of the crystal packing along b axis of the unit cell of the monomeric title complex [CuLCl].
Bottom Line: The potential tridentate Schiff base ligand 2-[1-(2-pyridyl-methyl-imino)eth-yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl-pyrrole with 2-amino-methyl-pyridine.The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl-amine as a base to deprotonate the pyrrole NH group.The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.

View Article: PubMed Central - HTML - PubMed

Affiliation: Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Teachers College, Huai'an 223300, Jiangsu Province, People's Republic of China.

ABSTRACT
The potential tridentate Schiff base ligand 2-[1-(2-pyridyl-methyl-imino)eth-yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl-pyrrole with 2-amino-methyl-pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl-amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.

No MeSH data available.


Related in: MedlinePlus