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catena-Poly[[[bis-(thio-urea-κS)copper(I)]-μ-thio-urea-κS:S] iodide acetonitrile hemisolvate].

Jia L, Kong LQ, Li DC - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thio-urea in acetonitrile.Each Cu(I) ion is in a distorted tetra-hedral coordination environment.The crystal structure is stabilized by weak N-H⋯S and N-H⋯I hydrogen bonds.

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ABSTRACT
The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thio-urea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thio-urea ligands to form a one-dimensional helical chain structure progagating in the a-axis direction. Each Cu(I) ion is in a distorted tetra-hedral coordination environment. The crystal structure is stabilized by weak N-H⋯S and N-H⋯I hydrogen bonds.

No MeSH data available.


Part of the one-dimensional helical chain structure of the title complex.
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Fap2: Part of the one-dimensional helical chain structure of the title complex.


catena-Poly[[[bis-(thio-urea-κS)copper(I)]-μ-thio-urea-κS:S] iodide acetonitrile hemisolvate].

Jia L, Kong LQ, Li DC - Acta Crystallogr Sect E Struct Rep Online (2008)

Part of the one-dimensional helical chain structure of the title complex.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960929&req=5

Fap2: Part of the one-dimensional helical chain structure of the title complex.
Bottom Line: The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thio-urea in acetonitrile.Each Cu(I) ion is in a distorted tetra-hedral coordination environment.The crystal structure is stabilized by weak N-H⋯S and N-H⋯I hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thio-urea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thio-urea ligands to form a one-dimensional helical chain structure progagating in the a-axis direction. Each Cu(I) ion is in a distorted tetra-hedral coordination environment. The crystal structure is stabilized by weak N-H⋯S and N-H⋯I hydrogen bonds.

No MeSH data available.