Limits...
Chloridotris[tris-(4-fluoro-phen-yl)phosphine]rhodium(I) methanol solvate.

Lorenzini F, Patrick BO, James BR - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The complex precipitates in trace amounts from a reaction between RhCl(cod)(thp) [cod is 1,5-cyclo-octa-diene and thp is tris-(hydroxy-meth-yl)phos-phine] and P(p-FC(6)H(4))(3) under argon in CD(3)OD.Two C(6)H(4)-F units are disordered over two positions; for one the site occupancy factors are ca. 0.53 and 0.47, for the other the values are ca. 0.64 and 0.36.The methyl H atoms of the solvent molecule are disordered across the mirror plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, Canada BC V6T 1Z1.

ABSTRACT
In the title compound, [RhCl{P(p-FC(6)H(4))(3)}(3)]·CH(3)OH, the Rh atom adopts a distorted square-planar geometry. Rh, Cl and one P atom lie on a mirror plane, as does the solvent molecule. There are two inter-molecular hydrogen bonds, one between the methanol O atom and an aryl H atom (2.51 Å), and one between the Cl atom and the hydr-oxy H atom of methanol [2.34 (3) Å]. The complex precipitates in trace amounts from a reaction between RhCl(cod)(thp) [cod is 1,5-cyclo-octa-diene and thp is tris-(hydroxy-meth-yl)phos-phine] and P(p-FC(6)H(4))(3) under argon in CD(3)OD. Two C(6)H(4)-F units are disordered over two positions; for one the site occupancy factors are ca. 0.53 and 0.47, for the other the values are ca. 0.64 and 0.36. The methyl H atoms of the solvent molecule are disordered across the mirror plane.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of title compound, with atom labeling scheme. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Only major part of disordered molecular moieties are presented.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2960913&req=5

Fap1: The molecular structure of title compound, with atom labeling scheme. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Only major part of disordered molecular moieties are presented.


Chloridotris[tris-(4-fluoro-phen-yl)phosphine]rhodium(I) methanol solvate.

Lorenzini F, Patrick BO, James BR - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of title compound, with atom labeling scheme. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Only major part of disordered molecular moieties are presented.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960913&req=5

Fap1: The molecular structure of title compound, with atom labeling scheme. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Only major part of disordered molecular moieties are presented.
Bottom Line: The complex precipitates in trace amounts from a reaction between RhCl(cod)(thp) [cod is 1,5-cyclo-octa-diene and thp is tris-(hydroxy-meth-yl)phos-phine] and P(p-FC(6)H(4))(3) under argon in CD(3)OD.Two C(6)H(4)-F units are disordered over two positions; for one the site occupancy factors are ca. 0.53 and 0.47, for the other the values are ca. 0.64 and 0.36.The methyl H atoms of the solvent molecule are disordered across the mirror plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, Canada BC V6T 1Z1.

ABSTRACT
In the title compound, [RhCl{P(p-FC(6)H(4))(3)}(3)]·CH(3)OH, the Rh atom adopts a distorted square-planar geometry. Rh, Cl and one P atom lie on a mirror plane, as does the solvent molecule. There are two inter-molecular hydrogen bonds, one between the methanol O atom and an aryl H atom (2.51 Å), and one between the Cl atom and the hydr-oxy H atom of methanol [2.34 (3) Å]. The complex precipitates in trace amounts from a reaction between RhCl(cod)(thp) [cod is 1,5-cyclo-octa-diene and thp is tris-(hydroxy-meth-yl)phos-phine] and P(p-FC(6)H(4))(3) under argon in CD(3)OD. Two C(6)H(4)-F units are disordered over two positions; for one the site occupancy factors are ca. 0.53 and 0.47, for the other the values are ca. 0.64 and 0.36. The methyl H atoms of the solvent molecule are disordered across the mirror plane.

No MeSH data available.


Related in: MedlinePlus