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Tetra-kis(μ-2,4-difluoro-benzoato)bis-[(2,4-difluoro-benzoato)(1,10-phenanthroline)gadolinium(III)].

Wang SB, He HM, Li S, Tang K - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluoro-benzoate and one 1,10-phenanthroline ligands.Two cations are linked into a centrosymmetric dimer via three bridging carboxyl-ate groups of 2,4-difluoro-benzoate ligands.Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms.

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ABSTRACT
In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluoro-benzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxyl-ate groups of 2,4-difluoro-benzoate ligands. Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms.

No MeSH data available.


The molecular structure of (I), showing 30% probability displacement ellipsoids. Unlabeled atoms are at the symmetry position (-x + 2, -y, -z + 2).
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Fap1: The molecular structure of (I), showing 30% probability displacement ellipsoids. Unlabeled atoms are at the symmetry position (-x + 2, -y, -z + 2).


Tetra-kis(μ-2,4-difluoro-benzoato)bis-[(2,4-difluoro-benzoato)(1,10-phenanthroline)gadolinium(III)].

Wang SB, He HM, Li S, Tang K - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of (I), showing 30% probability displacement ellipsoids. Unlabeled atoms are at the symmetry position (-x + 2, -y, -z + 2).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960912&req=5

Fap1: The molecular structure of (I), showing 30% probability displacement ellipsoids. Unlabeled atoms are at the symmetry position (-x + 2, -y, -z + 2).
Bottom Line: In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluoro-benzoate and one 1,10-phenanthroline ligands.Two cations are linked into a centrosymmetric dimer via three bridging carboxyl-ate groups of 2,4-difluoro-benzoate ligands.Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluoro-benzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxyl-ate groups of 2,4-difluoro-benzoate ligands. Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms.

No MeSH data available.