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trans-Diaqua-bis(ethyl-enediamine-κN,N')copper(II) bis[3-(3-pyrid-yl)propionate] dihydrate.

Moncol J, Segľa P, Mikloš D, Fischer A, Marian K - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol-ecule.The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn-Teller octa-hedral coordination is completed by two water O atoms in axial positions.In the crystal structure, intra- and inter-molecular N-H⋯O and O-H⋯O hydrogen bonds form a three-dimensional network.

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ABSTRACT
The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol-ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl-enediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn-Teller octa-hedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and inter-molecular N-H⋯O and O-H⋯O hydrogen bonds form a three-dimensional network.

No MeSH data available.


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A packing diagram of (I), showing hydrogen bonds and π-π stacking interactions, as dashed lines [symmetry codes: (iii) x + 1, y, z - 1; (iv) -x, -y + 2, -z + 1].
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Fap3: A packing diagram of (I), showing hydrogen bonds and π-π stacking interactions, as dashed lines [symmetry codes: (iii) x + 1, y, z - 1; (iv) -x, -y + 2, -z + 1].


trans-Diaqua-bis(ethyl-enediamine-κN,N')copper(II) bis[3-(3-pyrid-yl)propionate] dihydrate.

Moncol J, Segľa P, Mikloš D, Fischer A, Marian K - Acta Crystallogr Sect E Struct Rep Online (2008)

A packing diagram of (I), showing hydrogen bonds and π-π stacking interactions, as dashed lines [symmetry codes: (iii) x + 1, y, z - 1; (iv) -x, -y + 2, -z + 1].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960896&req=5

Fap3: A packing diagram of (I), showing hydrogen bonds and π-π stacking interactions, as dashed lines [symmetry codes: (iii) x + 1, y, z - 1; (iv) -x, -y + 2, -z + 1].
Bottom Line: The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol-ecule.The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn-Teller octa-hedral coordination is completed by two water O atoms in axial positions.In the crystal structure, intra- and inter-molecular N-H⋯O and O-H⋯O hydrogen bonds form a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title complex, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(8)H(8)NO(2))(2)·2H(2)O, contains one anion, one half-cation and one water mol-ecule. The Cu(II) atom in the [Cu(en)(2)(H(2)O)(2)](2+) cation (en is ethyl-enediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn-Teller octa-hedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and inter-molecular N-H⋯O and O-H⋯O hydrogen bonds form a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus