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catena-Poly[[[diaqua-cobalt(II)]bis-(μ-1,3-di-4-pyridylpropane-κN:N')] bis-(perchlorate) bis-(1,3-di-4-pyridyl-propane) bis-(2-methyl-4-nitro-aniline)].

Fu Z, Chen Y, Yi J - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment.The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol-ecule, one 2-methyl-4-nitro-aniline mol-ecule and one perchlorate anion.In the crystal structure, inter-molecular O-H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, People's Republic of China.

ABSTRACT
In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol-ecule, one 2-methyl-4-nitro-aniline mol-ecule and one perchlorate anion. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.

No MeSH data available.


Related in: MedlinePlus

The asymmetric unit of (I) with some symmetry related atoms. Displacement ellipsoids are drawn at the 50% probability level [Symmetry Codes: (a) -x, -1-y, -z, (b) x, -1+y, z, (c) -x, -y, -z].
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Fap1: The asymmetric unit of (I) with some symmetry related atoms. Displacement ellipsoids are drawn at the 50% probability level [Symmetry Codes: (a) -x, -1-y, -z, (b) x, -1+y, z, (c) -x, -y, -z].


catena-Poly[[[diaqua-cobalt(II)]bis-(μ-1,3-di-4-pyridylpropane-κN:N')] bis-(perchlorate) bis-(1,3-di-4-pyridyl-propane) bis-(2-methyl-4-nitro-aniline)].

Fu Z, Chen Y, Yi J - Acta Crystallogr Sect E Struct Rep Online (2008)

The asymmetric unit of (I) with some symmetry related atoms. Displacement ellipsoids are drawn at the 50% probability level [Symmetry Codes: (a) -x, -1-y, -z, (b) x, -1+y, z, (c) -x, -y, -z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960494&req=5

Fap1: The asymmetric unit of (I) with some symmetry related atoms. Displacement ellipsoids are drawn at the 50% probability level [Symmetry Codes: (a) -x, -1-y, -z, (b) x, -1+y, z, (c) -x, -y, -z].
Bottom Line: In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment.The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol-ecule, one 2-methyl-4-nitro-aniline mol-ecule and one perchlorate anion.In the crystal structure, inter-molecular O-H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, People's Republic of China.

ABSTRACT
In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol-ecule, one 2-methyl-4-nitro-aniline mol-ecule and one perchlorate anion. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.

No MeSH data available.


Related in: MedlinePlus