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S-Benzyl-thiouronium 4-anilinobenzene-sulfonate.

Fun HK, Chantrapromma S, D'Silva ED, Patil PS, Dharmaprakash SM - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the 4-anilinobenzene-sulfonate anion, the inter-planar angle between the two rings is 44.07 (8)°.In the crystal structure, anions are linked into chains along the c-axis direction by N-H⋯O hydrogen bonds, while additional N-H⋯O inter-actions link the cations to the anions in chains along the b-axis direction.These chains are further inter-connected into a two-dimensional network parallel to the bc plane by C-H⋯O inter-actions.

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ABSTRACT
In the title compound, C(8)H(11)N(2)S(+)·C(12)H(10)NO(3)S(-), the NH group of the S-benzyl-thiuronium is protonated and the inter-planar angle between the phenyl ring and the CH(2)-S=C(NH(2))(2) unit is 47.44 (10)°. In the 4-anilinobenzene-sulfonate anion, the inter-planar angle between the two rings is 44.07 (8)°. In the crystal structure, anions are linked into chains along the c-axis direction by N-H⋯O hydrogen bonds, while additional N-H⋯O inter-actions link the cations to the anions in chains along the b-axis direction. These chains are further inter-connected into a two-dimensional network parallel to the bc plane by C-H⋯O inter-actions. C-H⋯π contacts are also observed.

No MeSH data available.


Related in: MedlinePlus

The asymmetric unit of (I), showing 50% probability displacement ellipsoids and the atomic numbering. The N—H···O hydrogen bond is drawn as a dashed line.
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Fap1: The asymmetric unit of (I), showing 50% probability displacement ellipsoids and the atomic numbering. The N—H···O hydrogen bond is drawn as a dashed line.


S-Benzyl-thiouronium 4-anilinobenzene-sulfonate.

Fun HK, Chantrapromma S, D'Silva ED, Patil PS, Dharmaprakash SM - Acta Crystallogr Sect E Struct Rep Online (2008)

The asymmetric unit of (I), showing 50% probability displacement ellipsoids and the atomic numbering. The N—H···O hydrogen bond is drawn as a dashed line.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960486&req=5

Fap1: The asymmetric unit of (I), showing 50% probability displacement ellipsoids and the atomic numbering. The N—H···O hydrogen bond is drawn as a dashed line.
Bottom Line: In the 4-anilinobenzene-sulfonate anion, the inter-planar angle between the two rings is 44.07 (8)°.In the crystal structure, anions are linked into chains along the c-axis direction by N-H⋯O hydrogen bonds, while additional N-H⋯O inter-actions link the cations to the anions in chains along the b-axis direction.These chains are further inter-connected into a two-dimensional network parallel to the bc plane by C-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(8)H(11)N(2)S(+)·C(12)H(10)NO(3)S(-), the NH group of the S-benzyl-thiuronium is protonated and the inter-planar angle between the phenyl ring and the CH(2)-S=C(NH(2))(2) unit is 47.44 (10)°. In the 4-anilinobenzene-sulfonate anion, the inter-planar angle between the two rings is 44.07 (8)°. In the crystal structure, anions are linked into chains along the c-axis direction by N-H⋯O hydrogen bonds, while additional N-H⋯O inter-actions link the cations to the anions in chains along the b-axis direction. These chains are further inter-connected into a two-dimensional network parallel to the bc plane by C-H⋯O inter-actions. C-H⋯π contacts are also observed.

No MeSH data available.


Related in: MedlinePlus