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catena-Poly[[tetra-aqua-zinc(II)]-μ-2,2'-dihydr-oxy-5,5'-diazenediyldibenzoato].

Tan YH, Li QS, Luo XP, Xie XB - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The Zn(II) atom is hexa-coordinated in a distorted octa-hedral geometry by six O atoms [Zn-O = 2.055 (4)-2.132 (3) Å] from two carboxylate ligands and four water mol-ecules.The crystal packing is stabilized by inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, and two π-π inter-actions.The centroid-centroid distances are 3.803 (16) and 3.804 (17) Å.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Zn(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), the 2,2'-dihydr-oxy-5,5'-diazenediyldibenzoate ligand acts as a carboxyl-ate bridge, leading to the formation of a polymeric chain running along the [10] direction. The Zn(II) atom is hexa-coordinated in a distorted octa-hedral geometry by six O atoms [Zn-O = 2.055 (4)-2.132 (3) Å] from two carboxylate ligands and four water mol-ecules. The crystal packing is stabilized by inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, and two π-π inter-actions. The centroid-centroid distances are 3.803 (16) and 3.804 (17) Å.

No MeSH data available.


A part of the polymeric structure of (I), showing displacement ellipsoids drawn at the 30% probability level and the atomic labelling. Unlabelled atoms are related to labelled atoms by the symmetry code (x - 1, y + 1, z).
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Fap1: A part of the polymeric structure of (I), showing displacement ellipsoids drawn at the 30% probability level and the atomic labelling. Unlabelled atoms are related to labelled atoms by the symmetry code (x - 1, y + 1, z).


catena-Poly[[tetra-aqua-zinc(II)]-μ-2,2'-dihydr-oxy-5,5'-diazenediyldibenzoato].

Tan YH, Li QS, Luo XP, Xie XB - Acta Crystallogr Sect E Struct Rep Online (2008)

A part of the polymeric structure of (I), showing displacement ellipsoids drawn at the 30% probability level and the atomic labelling. Unlabelled atoms are related to labelled atoms by the symmetry code (x - 1, y + 1, z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960379&req=5

Fap1: A part of the polymeric structure of (I), showing displacement ellipsoids drawn at the 30% probability level and the atomic labelling. Unlabelled atoms are related to labelled atoms by the symmetry code (x - 1, y + 1, z).
Bottom Line: The Zn(II) atom is hexa-coordinated in a distorted octa-hedral geometry by six O atoms [Zn-O = 2.055 (4)-2.132 (3) Å] from two carboxylate ligands and four water mol-ecules.The crystal packing is stabilized by inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, and two π-π inter-actions.The centroid-centroid distances are 3.803 (16) and 3.804 (17) Å.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Zn(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), the 2,2'-dihydr-oxy-5,5'-diazenediyldibenzoate ligand acts as a carboxyl-ate bridge, leading to the formation of a polymeric chain running along the [10] direction. The Zn(II) atom is hexa-coordinated in a distorted octa-hedral geometry by six O atoms [Zn-O = 2.055 (4)-2.132 (3) Å] from two carboxylate ligands and four water mol-ecules. The crystal packing is stabilized by inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, and two π-π inter-actions. The centroid-centroid distances are 3.803 (16) and 3.804 (17) Å.

No MeSH data available.