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Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κN,O]cadmium(II) 1.75-hydrate.

Kai Z, Yin XH, Yu F, Zhu J, Lin CW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa-hedral geometry.Three water mol-ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit.The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network.

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ABSTRACT
In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa-hedral geometry. Three water mol-ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit. The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network.

No MeSH data available.


Crystal packing in (I) showing the hydrogen bonding interactions as dashed lines.
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Fap2: Crystal packing in (I) showing the hydrogen bonding interactions as dashed lines.


Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κN,O]cadmium(II) 1.75-hydrate.

Kai Z, Yin XH, Yu F, Zhu J, Lin CW - Acta Crystallogr Sect E Struct Rep Online (2008)

Crystal packing in (I) showing the hydrogen bonding interactions as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960373&req=5

Fap2: Crystal packing in (I) showing the hydrogen bonding interactions as dashed lines.
Bottom Line: In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa-hedral geometry.Three water mol-ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit.The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa-hedral geometry. Three water mol-ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit. The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network.

No MeSH data available.