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[μ-N,N'-Bis(3-meth-oxy-2-oxidobenzyl-idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate.

Fei L, Fang Z - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: Naturforsch.Teil B, 59, 535-540], which was described in the space group P1 with two formula units in the asymmetric unit.The crystal stucture is, in fact, centrosymmetric and is described here in the space group P with one formula unit in the asymmetric unit.

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Affiliation: The College of Chemical Engineering & Materials, Eastern Liaoning University, 325 Wenhua Road, Yuanbao District, Dandong City, Liaoning Province 118003, People's Republic of China.

ABSTRACT
In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordin-ated by four O atoms from the deprotonated Schiff base and six O atoms from three bidentate nitrate anions. The compound is isostructural with the previously reported Gd(III) analogue [Elmali & Elerman (2004 ▶). Z. Naturforsch. Teil B, 59, 535-540], which was described in the space group P1 with two formula units in the asymmetric unit. The crystal stucture is, in fact, centrosymmetric and is described here in the space group P with one formula unit in the asymmetric unit.

No MeSH data available.


The molecular structure, showing 40% probability displacement ellipsoids for non-H atoms. The acetone solvent molecule is not shown.
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Fap1: The molecular structure, showing 40% probability displacement ellipsoids for non-H atoms. The acetone solvent molecule is not shown.


[μ-N,N'-Bis(3-meth-oxy-2-oxidobenzyl-idene)propane-1,3-diamine]trinitratocopper(II)terbium(III) acetone solvate.

Fei L, Fang Z - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure, showing 40% probability displacement ellipsoids for non-H atoms. The acetone solvent molecule is not shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960331&req=5

Fap1: The molecular structure, showing 40% probability displacement ellipsoids for non-H atoms. The acetone solvent molecule is not shown.
Bottom Line: Naturforsch.Teil B, 59, 535-540], which was described in the space group P1 with two formula units in the asymmetric unit.The crystal stucture is, in fact, centrosymmetric and is described here in the space group P with one formula unit in the asymmetric unit.

View Article: PubMed Central - HTML - PubMed

Affiliation: The College of Chemical Engineering & Materials, Eastern Liaoning University, 325 Wenhua Road, Yuanbao District, Dandong City, Liaoning Province 118003, People's Republic of China.

ABSTRACT
In the title complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) atom is four-coordinated by two O atoms and two N atoms from the deprotonated Schiff base in a square-planar geometry, while the Tb(III) atom is ten-coordin-ated by four O atoms from the deprotonated Schiff base and six O atoms from three bidentate nitrate anions. The compound is isostructural with the previously reported Gd(III) analogue [Elmali & Elerman (2004 ▶). Z. Naturforsch. Teil B, 59, 535-540], which was described in the space group P1 with two formula units in the asymmetric unit. The crystal stucture is, in fact, centrosymmetric and is described here in the space group P with one formula unit in the asymmetric unit.

No MeSH data available.