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Poly[hexa-aqua-copper(II) [di-μ(3)-sulfato-disodiate(I)]].

Wu W, Xie JM, Xie DP, Xuan YW - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: Copper occupies a special position ().The Na atom is coordinated by five O atoms of four sulfates [Na-O distances are between 2.825 (3) and 2.983 (3) Å].The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetra-dentate mode.

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ABSTRACT
The title compound, {[Cu(H(2)O)(6)][Na(2)(SO(4))(2)]}(n), has been prepared under mild hydro-thermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (). The Na atom is coordinated by five O atoms of four sulfates [Na-O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetra-dentate mode.

No MeSH data available.


[Na2(SO4)2]n2n- network in title compound 1.
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Fap2: [Na2(SO4)2]n2n- network in title compound 1.


Poly[hexa-aqua-copper(II) [di-μ(3)-sulfato-disodiate(I)]].

Wu W, Xie JM, Xie DP, Xuan YW - Acta Crystallogr Sect E Struct Rep Online (2008)

[Na2(SO4)2]n2n- network in title compound 1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960320&req=5

Fap2: [Na2(SO4)2]n2n- network in title compound 1.
Bottom Line: Copper occupies a special position ().The Na atom is coordinated by five O atoms of four sulfates [Na-O distances are between 2.825 (3) and 2.983 (3) Å].The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetra-dentate mode.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, {[Cu(H(2)O)(6)][Na(2)(SO(4))(2)]}(n), has been prepared under mild hydro-thermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position (). The Na atom is coordinated by five O atoms of four sulfates [Na-O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetra-dentate mode.

No MeSH data available.