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catena-Poly[[[aqua-(propane-1,3-diamine-κN,N')copper(II)]-μ-fumarato-κO:O'] monohydrate].

Padmanabhan M, Joseph JC, Olsson S, Bakir M - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: A longer Cu-O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework.One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type.O-H⋯O and N-H⋯O hydrogen bonds are observed in the crystal structure.

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ABSTRACT
The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu-O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type. O-H⋯O and N-H⋯O hydrogen bonds are observed in the crystal structure.

No MeSH data available.


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Part of a zigzag polymeric chain of the title compound. Hydrogen bonds are shown as dashed lines.
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Fap2: Part of a zigzag polymeric chain of the title compound. Hydrogen bonds are shown as dashed lines.


catena-Poly[[[aqua-(propane-1,3-diamine-κN,N')copper(II)]-μ-fumarato-κO:O'] monohydrate].

Padmanabhan M, Joseph JC, Olsson S, Bakir M - Acta Crystallogr Sect E Struct Rep Online (2008)

Part of a zigzag polymeric chain of the title compound. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960309&req=5

Fap2: Part of a zigzag polymeric chain of the title compound. Hydrogen bonds are shown as dashed lines.
Bottom Line: A longer Cu-O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework.One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type.O-H⋯O and N-H⋯O hydrogen bonds are observed in the crystal structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu-O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type. O-H⋯O and N-H⋯O hydrogen bonds are observed in the crystal structure.

No MeSH data available.


Related in: MedlinePlus