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Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).

Zhou XX, Zhou ZY, Chen JQ, Lin XM, Cai YP - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans).The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Environment, South China Normal University, Guangzhou 510631, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.

No MeSH data available.


A view of the three-dimensional molecular network parallel to (010), formed by weak intermolecular C—H···S hydrogen bonds (dotted lines). Hydrogen atoms not involved in hydrogen bonds have been omitted.
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Fap2: A view of the three-dimensional molecular network parallel to (010), formed by weak intermolecular C—H···S hydrogen bonds (dotted lines). Hydrogen atoms not involved in hydrogen bonds have been omitted.


Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).

Zhou XX, Zhou ZY, Chen JQ, Lin XM, Cai YP - Acta Crystallogr Sect E Struct Rep Online (2008)

A view of the three-dimensional molecular network parallel to (010), formed by weak intermolecular C—H···S hydrogen bonds (dotted lines). Hydrogen atoms not involved in hydrogen bonds have been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960303&req=5

Fap2: A view of the three-dimensional molecular network parallel to (010), formed by weak intermolecular C—H···S hydrogen bonds (dotted lines). Hydrogen atoms not involved in hydrogen bonds have been omitted.
Bottom Line: In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans).The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Environment, South China Normal University, Guangzhou 510631, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.

No MeSH data available.