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Diammonium bis-[(2-amino-acetato-κN,O)(2,2'-bipyridine-κN,N')(N,N-dimethyl-formamide-κO)copper(II)] hexa-cosa-oxidoocta-molybdate(VI).

Liu H, Zhang Y, Yu D - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions.The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical position.The anions and cations are linked by N-H⋯O hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Pharmacy, Jiamusi University, Jiamusi 154007, People's Republic of China.

ABSTRACT
The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical position. The anions and cations are linked by N-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.


Crystal packing of the title compound. The ammonium ions are drawn as ball. Dotted lines denote hydrogen bonds.
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Fap2: Crystal packing of the title compound. The ammonium ions are drawn as ball. Dotted lines denote hydrogen bonds.


Diammonium bis-[(2-amino-acetato-κN,O)(2,2'-bipyridine-κN,N')(N,N-dimethyl-formamide-κO)copper(II)] hexa-cosa-oxidoocta-molybdate(VI).

Liu H, Zhang Y, Yu D - Acta Crystallogr Sect E Struct Rep Online (2008)

Crystal packing of the title compound. The ammonium ions are drawn as ball. Dotted lines denote hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960279&req=5

Fap2: Crystal packing of the title compound. The ammonium ions are drawn as ball. Dotted lines denote hydrogen bonds.
Bottom Line: The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions.The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical position.The anions and cations are linked by N-H⋯O hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Pharmacy, Jiamusi University, Jiamusi 154007, People's Republic of China.

ABSTRACT
The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical position. The anions and cations are linked by N-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.