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Dichlorido(dimethyl-glyoximato-κN,N')(dimethyl-glyoxime-κN,N')cobalt(III).

Ramesh P, Subbiahpandi A, Jothi P, Revathi C, Dayalan A - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: Strong intra-molecular O-H⋯O hydrogen bonds are observed between the dimethyl-glyoxime and dimethyl-glyoximate ligands.Mol-ecules are linked into a chain running along the [101] direction by O-H⋯O and C-H⋯Cl hydrogen bonds.The chains are cross-linked through inter-molecular C-H⋯Cl hydrogen bonds.

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ABSTRACT
In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa-hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl-glyoxime and dimethyl-glyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intra-molecular O-H⋯O hydrogen bonds are observed between the dimethyl-glyoxime and dimethyl-glyoximate ligands. Mol-ecules are linked into a chain running along the [101] direction by O-H⋯O and C-H⋯Cl hydrogen bonds. The chains are cross-linked through inter-molecular C-H⋯Cl hydrogen bonds.

No MeSH data available.


The structure of the title complex. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitary radii.
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Fap1: The structure of the title complex. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitary radii.


Dichlorido(dimethyl-glyoximato-κN,N')(dimethyl-glyoxime-κN,N')cobalt(III).

Ramesh P, Subbiahpandi A, Jothi P, Revathi C, Dayalan A - Acta Crystallogr Sect E Struct Rep Online (2008)

The structure of the title complex. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960257&req=5

Fap1: The structure of the title complex. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitary radii.
Bottom Line: Strong intra-molecular O-H⋯O hydrogen bonds are observed between the dimethyl-glyoxime and dimethyl-glyoximate ligands.Mol-ecules are linked into a chain running along the [101] direction by O-H⋯O and C-H⋯Cl hydrogen bonds.The chains are cross-linked through inter-molecular C-H⋯Cl hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa-hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl-glyoxime and dimethyl-glyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intra-molecular O-H⋯O hydrogen bonds are observed between the dimethyl-glyoxime and dimethyl-glyoximate ligands. Mol-ecules are linked into a chain running along the [101] direction by O-H⋯O and C-H⋯Cl hydrogen bonds. The chains are cross-linked through inter-molecular C-H⋯Cl hydrogen bonds.

No MeSH data available.