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(2,3,5,10,12,13,15,20-Octa-phenyl-porphinato)copper(II) 1,1,2,2-tetra-chloro-ethane solvate.

Bhyrappa P, Karunanithi K, Varghese B - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title complex, [Cu(C(68)H(44)N(4))]·C(2)H(2)Cl(4), exhibits nearly square-planar geometry around the Cu(II) centre and the macrocyclic ring is almost planar.Further, it has non-crystallographic twofold rotation axis and mirror plane (C(s)) symmetry perpendicular to the mol-ecular plane.The mol-ecular packing of the complexes and the solvent molecules shows weak inter-molecular C-H⋯π, C-H⋯Cl and C-H⋯N inter-actions, forming a clathrate-like structure.

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ABSTRACT
The title complex, [Cu(C(68)H(44)N(4))]·C(2)H(2)Cl(4), exhibits nearly square-planar geometry around the Cu(II) centre and the macrocyclic ring is almost planar. The porphyrin mol-ecule has an approximate non-crystallographic inversion centre (C(i)), and a non-crystallographic twofold rotation axis (C(2)) within the Cu(II)-porphyrin ring plane. Further, it has non-crystallographic twofold rotation axis and mirror plane (C(s)) symmetry perpendicular to the mol-ecular plane. The mol-ecular packing of the complexes and the solvent molecules shows weak inter-molecular C-H⋯π, C-H⋯Cl and C-H⋯N inter-actions, forming a clathrate-like structure.

No MeSH data available.


Related in: MedlinePlus

View of the molecular packing of interconnecting two arrays to form a two-dimensional network of the title structure. Color scheme: C, H, gray; N, blue; Cl, green; Cu, red. The dotted red lines show the inter-array hydrogen bonding C—H···Cl (H67···Cl4) and C—H···π (H66···C18) interactions.
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Fap3: View of the molecular packing of interconnecting two arrays to form a two-dimensional network of the title structure. Color scheme: C, H, gray; N, blue; Cl, green; Cu, red. The dotted red lines show the inter-array hydrogen bonding C—H···Cl (H67···Cl4) and C—H···π (H66···C18) interactions.


(2,3,5,10,12,13,15,20-Octa-phenyl-porphinato)copper(II) 1,1,2,2-tetra-chloro-ethane solvate.

Bhyrappa P, Karunanithi K, Varghese B - Acta Crystallogr Sect E Struct Rep Online (2008)

View of the molecular packing of interconnecting two arrays to form a two-dimensional network of the title structure. Color scheme: C, H, gray; N, blue; Cl, green; Cu, red. The dotted red lines show the inter-array hydrogen bonding C—H···Cl (H67···Cl4) and C—H···π (H66···C18) interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960240&req=5

Fap3: View of the molecular packing of interconnecting two arrays to form a two-dimensional network of the title structure. Color scheme: C, H, gray; N, blue; Cl, green; Cu, red. The dotted red lines show the inter-array hydrogen bonding C—H···Cl (H67···Cl4) and C—H···π (H66···C18) interactions.
Bottom Line: The title complex, [Cu(C(68)H(44)N(4))]·C(2)H(2)Cl(4), exhibits nearly square-planar geometry around the Cu(II) centre and the macrocyclic ring is almost planar.Further, it has non-crystallographic twofold rotation axis and mirror plane (C(s)) symmetry perpendicular to the mol-ecular plane.The mol-ecular packing of the complexes and the solvent molecules shows weak inter-molecular C-H⋯π, C-H⋯Cl and C-H⋯N inter-actions, forming a clathrate-like structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [Cu(C(68)H(44)N(4))]·C(2)H(2)Cl(4), exhibits nearly square-planar geometry around the Cu(II) centre and the macrocyclic ring is almost planar. The porphyrin mol-ecule has an approximate non-crystallographic inversion centre (C(i)), and a non-crystallographic twofold rotation axis (C(2)) within the Cu(II)-porphyrin ring plane. Further, it has non-crystallographic twofold rotation axis and mirror plane (C(s)) symmetry perpendicular to the mol-ecular plane. The mol-ecular packing of the complexes and the solvent molecules shows weak inter-molecular C-H⋯π, C-H⋯Cl and C-H⋯N inter-actions, forming a clathrate-like structure.

No MeSH data available.


Related in: MedlinePlus