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catena-Poly[silver(I)-μ-pyrazolato-κN:N'].

Zhang CY, Feng JB, Gao Q, Xie YB - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The X-ray single-crystal diffraction result is consonant with that of the ab initio X-ray powder diffraction reported by Masciocchi, Moret, Cairati, Sironi, Ardizzoia & La Monica [J.Chem.Soc. (1994). 116, 7668-7676], with only minor deviations of structural parameters.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, People's Republic of China.

ABSTRACT
The title compound, [Ag(C(3)H(3)N(2))](n), has an infinite helical chain structure in which each pyrazolate group bridges two Ag(I) atoms related by a 2(1) axis with an intra-chain Ag⋯Ag separation of 3.3718 (7) Å. Each Ag(I) center is linearly coordinated by two N atoms [N-Ag-N angle = 169.98 (14)°]. The chains are held together by inter-chain Ag⋯Ag inter-actions [3.2547 (6) Å], forming a two-dimensional layer. The X-ray single-crystal diffraction result is consonant with that of the ab initio X-ray powder diffraction reported by Masciocchi, Moret, Cairati, Sironi, Ardizzoia & La Monica [J. Am. Chem. Soc. (1994). 116, 7668-7676], with only minor deviations of structural parameters.

No MeSH data available.


Related in: MedlinePlus

Displacement ellipsoid plot (30% probability) of (I). [symmetry codes: (A) x - 1/2, 1/2 - y, 2 - z; (B) x + 1/2, 1/2 - y, 2 - z]
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Fap1: Displacement ellipsoid plot (30% probability) of (I). [symmetry codes: (A) x - 1/2, 1/2 - y, 2 - z; (B) x + 1/2, 1/2 - y, 2 - z]


catena-Poly[silver(I)-μ-pyrazolato-κN:N'].

Zhang CY, Feng JB, Gao Q, Xie YB - Acta Crystallogr Sect E Struct Rep Online (2008)

Displacement ellipsoid plot (30% probability) of (I). [symmetry codes: (A) x - 1/2, 1/2 - y, 2 - z; (B) x + 1/2, 1/2 - y, 2 - z]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960218&req=5

Fap1: Displacement ellipsoid plot (30% probability) of (I). [symmetry codes: (A) x - 1/2, 1/2 - y, 2 - z; (B) x + 1/2, 1/2 - y, 2 - z]
Bottom Line: The X-ray single-crystal diffraction result is consonant with that of the ab initio X-ray powder diffraction reported by Masciocchi, Moret, Cairati, Sironi, Ardizzoia & La Monica [J.Chem.Soc. (1994). 116, 7668-7676], with only minor deviations of structural parameters.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, People's Republic of China.

ABSTRACT
The title compound, [Ag(C(3)H(3)N(2))](n), has an infinite helical chain structure in which each pyrazolate group bridges two Ag(I) atoms related by a 2(1) axis with an intra-chain Ag⋯Ag separation of 3.3718 (7) Å. Each Ag(I) center is linearly coordinated by two N atoms [N-Ag-N angle = 169.98 (14)°]. The chains are held together by inter-chain Ag⋯Ag inter-actions [3.2547 (6) Å], forming a two-dimensional layer. The X-ray single-crystal diffraction result is consonant with that of the ab initio X-ray powder diffraction reported by Masciocchi, Moret, Cairati, Sironi, Ardizzoia & La Monica [J. Am. Chem. Soc. (1994). 116, 7668-7676], with only minor deviations of structural parameters.

No MeSH data available.


Related in: MedlinePlus