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Bis(acetato-κO)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κN,N']copper(II).

Slootweg JC, Chen P - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry.In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry.The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯O hydrogen-bonding contacts.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule (ETH) Zürich, Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland.

ABSTRACT
In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯O hydrogen-bonding contacts.

No MeSH data available.


Displacement ellipsoid of [(TMEDA)Cu(OAc)2] with ellipsoids drawn at the 50% probability level. Weak interactions in the metal coordination sphere are shown as dotted lines. Hydrogen atoms are omitted for clarity.
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Fap1: Displacement ellipsoid of [(TMEDA)Cu(OAc)2] with ellipsoids drawn at the 50% probability level. Weak interactions in the metal coordination sphere are shown as dotted lines. Hydrogen atoms are omitted for clarity.


Bis(acetato-κO)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κN,N']copper(II).

Slootweg JC, Chen P - Acta Crystallogr Sect E Struct Rep Online (2008)

Displacement ellipsoid of [(TMEDA)Cu(OAc)2] with ellipsoids drawn at the 50% probability level. Weak interactions in the metal coordination sphere are shown as dotted lines. Hydrogen atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960195&req=5

Fap1: Displacement ellipsoid of [(TMEDA)Cu(OAc)2] with ellipsoids drawn at the 50% probability level. Weak interactions in the metal coordination sphere are shown as dotted lines. Hydrogen atoms are omitted for clarity.
Bottom Line: In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry.In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry.The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯O hydrogen-bonding contacts.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule (ETH) Zürich, Wolfgang-Pauli-Strasse 10, 8093 Zürich, Switzerland.

ABSTRACT
In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯O hydrogen-bonding contacts.

No MeSH data available.