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(E)-N-[2-(9-Fluorenyl-idene)-3a,5,7-tri-methyl-3,3a-dihydro-2H-indol-3-yl-idene]-2,4,6-trimethyl-aniline.

Mizuhata Y, Tokitoh N - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond.The angle between the least-squares planes of the imine C=N-C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°.The crystal structure is sustained mainly by inter-molecular π-π inter-actions (3.510 Å) between the two fluorene rings and some C-H⋯π inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan.

ABSTRACT
The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N-C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°. The crystal structure is sustained mainly by inter-molecular π-π inter-actions (3.510 Å) between the two fluorene rings and some C-H⋯π inter-actions.

No MeSH data available.


Related in: MedlinePlus

The molecular packing of the title compound. Dashed lines indicate the C–H···π intramolecular contacts [Symmetry codes: (i) -x, -y, -z; (ii) 1 + x, +y, +z; (iii) 1/2 + x, 1/2 - y, 1/2 + z].
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Fap2: The molecular packing of the title compound. Dashed lines indicate the C–H···π intramolecular contacts [Symmetry codes: (i) -x, -y, -z; (ii) 1 + x, +y, +z; (iii) 1/2 + x, 1/2 - y, 1/2 + z].


(E)-N-[2-(9-Fluorenyl-idene)-3a,5,7-tri-methyl-3,3a-dihydro-2H-indol-3-yl-idene]-2,4,6-trimethyl-aniline.

Mizuhata Y, Tokitoh N - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular packing of the title compound. Dashed lines indicate the C–H···π intramolecular contacts [Symmetry codes: (i) -x, -y, -z; (ii) 1 + x, +y, +z; (iii) 1/2 + x, 1/2 - y, 1/2 + z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960190&req=5

Fap2: The molecular packing of the title compound. Dashed lines indicate the C–H···π intramolecular contacts [Symmetry codes: (i) -x, -y, -z; (ii) 1 + x, +y, +z; (iii) 1/2 + x, 1/2 - y, 1/2 + z].
Bottom Line: The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond.The angle between the least-squares planes of the imine C=N-C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°.The crystal structure is sustained mainly by inter-molecular π-π inter-actions (3.510 Å) between the two fluorene rings and some C-H⋯π inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan.

ABSTRACT
The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N-C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°. The crystal structure is sustained mainly by inter-molecular π-π inter-actions (3.510 Å) between the two fluorene rings and some C-H⋯π inter-actions.

No MeSH data available.


Related in: MedlinePlus