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Bis(2-methyl-4-nitro-anilinium) tetra-chloridomercurate(II).

Dinesh J, Rademeyer M, Billing DG, Lemmerer A - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro-anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra-hedral [HgCl(4)](2-) groups.The organic sheets are inter-linked through weak C-H⋯O hydrogen bonds, while they inter-act with the anionic part via strong charge-assisted N(+)-H⋯Cl-Hg hydrogen bonds.The [HgCl(4)](2-) anions are bis-ected by a mirror plane passing through the metal and two of the chloride ions.

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ABSTRACT
The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro-anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra-hedral [HgCl(4)](2-) groups. The organic sheets are inter-linked through weak C-H⋯O hydrogen bonds, while they inter-act with the anionic part via strong charge-assisted N(+)-H⋯Cl-Hg hydrogen bonds. The [HgCl(4)](2-) anions are bis-ected by a mirror plane passing through the metal and two of the chloride ions.

No MeSH data available.


Atom labelling scheme of (I) with thermal ellipsoids drawn at the 50% probability level. The Cl atom marked with a prime (') is at symmetry position (1/2 + x, 1/2 - y, 1/2 - z).
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Fap1: Atom labelling scheme of (I) with thermal ellipsoids drawn at the 50% probability level. The Cl atom marked with a prime (') is at symmetry position (1/2 + x, 1/2 - y, 1/2 - z).


Bis(2-methyl-4-nitro-anilinium) tetra-chloridomercurate(II).

Dinesh J, Rademeyer M, Billing DG, Lemmerer A - Acta Crystallogr Sect E Struct Rep Online (2008)

Atom labelling scheme of (I) with thermal ellipsoids drawn at the 50% probability level. The Cl atom marked with a prime (') is at symmetry position (1/2 + x, 1/2 - y, 1/2 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960147&req=5

Fap1: Atom labelling scheme of (I) with thermal ellipsoids drawn at the 50% probability level. The Cl atom marked with a prime (') is at symmetry position (1/2 + x, 1/2 - y, 1/2 - z).
Bottom Line: The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro-anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra-hedral [HgCl(4)](2-) groups.The organic sheets are inter-linked through weak C-H⋯O hydrogen bonds, while they inter-act with the anionic part via strong charge-assisted N(+)-H⋯Cl-Hg hydrogen bonds.The [HgCl(4)](2-) anions are bis-ected by a mirror plane passing through the metal and two of the chloride ions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro-anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra-hedral [HgCl(4)](2-) groups. The organic sheets are inter-linked through weak C-H⋯O hydrogen bonds, while they inter-act with the anionic part via strong charge-assisted N(+)-H⋯Cl-Hg hydrogen bonds. The [HgCl(4)](2-) anions are bis-ected by a mirror plane passing through the metal and two of the chloride ions.

No MeSH data available.