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A bi-TTF with a bipyridine spacer: 4,4'-bis-[(3,6,7-trimethyl-sulfanyltetra-thia-fulvalen-2-yl)sulfanylmeth-yl]-2,2'-bipyridine.

Kaboub L, Fabre JM, Legros JP - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The complete molecule is generated by a crystallographic inversion centre.In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)°.There is a short S⋯S contact [3.4863  (14) Å] in the crystal structure.

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ABSTRACT
The title compound, C(30)H(28)N(2)S(16), is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)°. There is a short S⋯S contact [3.4863  (14) Å] in the crystal structure.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound, with atom labels and 50% probability displacement ellipsoids for non-H atoms. Symmetry code: i = -x+1, -y+1, -z+1.
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Fap1: The molecular structure of the title compound, with atom labels and 50% probability displacement ellipsoids for non-H atoms. Symmetry code: i = -x+1, -y+1, -z+1.


A bi-TTF with a bipyridine spacer: 4,4'-bis-[(3,6,7-trimethyl-sulfanyltetra-thia-fulvalen-2-yl)sulfanylmeth-yl]-2,2'-bipyridine.

Kaboub L, Fabre JM, Legros JP - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound, with atom labels and 50% probability displacement ellipsoids for non-H atoms. Symmetry code: i = -x+1, -y+1, -z+1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960116&req=5

Fap1: The molecular structure of the title compound, with atom labels and 50% probability displacement ellipsoids for non-H atoms. Symmetry code: i = -x+1, -y+1, -z+1.
Bottom Line: The complete molecule is generated by a crystallographic inversion centre.In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)°.There is a short S⋯S contact [3.4863  (14) Å] in the crystal structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(30)H(28)N(2)S(16), is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)°. There is a short S⋯S contact [3.4863  (14) Å] in the crystal structure.

No MeSH data available.


Related in: MedlinePlus