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Penta-carbonyl-2κC-chlorido-1κCl-bis-[1(η)-cyclo-penta-dien-yl](μ-α-oxido-benzyl-idene-1:2κO:C)titanium(IV)tungsten(0).

Esterhuysen C, Nel IB, Esterhuysen MW, Cronje S - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride.The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane.One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa.

ABSTRACT
The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.

No MeSH data available.


The molecular structure of (I) showing the atomic labelling scheme and displacement ellipsoids drawn at the 50% probability level.
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Fap1: The molecular structure of (I) showing the atomic labelling scheme and displacement ellipsoids drawn at the 50% probability level.


Penta-carbonyl-2κC-chlorido-1κCl-bis-[1(η)-cyclo-penta-dien-yl](μ-α-oxido-benzyl-idene-1:2κO:C)titanium(IV)tungsten(0).

Esterhuysen C, Nel IB, Esterhuysen MW, Cronje S - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of (I) showing the atomic labelling scheme and displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960115&req=5

Fap1: The molecular structure of (I) showing the atomic labelling scheme and displacement ellipsoids drawn at the 50% probability level.
Bottom Line: The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride.The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane.One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa.

ABSTRACT
The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.

No MeSH data available.