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catena-Poly[[bis-(μ(2)-4-amino-benzene-sulfonato-κO:O)disilver]-bis-(μ(2)-4,4'-bipyridine-κN:N')].

Ou GC, Zhang M, Yuan XY, Dai YQ - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) and two O atoms from two independent 4-amino-benzene-sulfonate (ABS) ligands.The two inter-chain Ag(I) atoms are bridged by two independent ABS ligands through weak Ag-O bonds and Ag⋯Ag attractions, forming a ladder-like chain coordination polymer [Ag(2)(ABS)(2)(bipy)(2)](n) parallel to [001], which is further linked to generate a two-dimensional structure via N-H⋯O hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425100, People's Republic of China.

ABSTRACT
In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) and two O atoms from two independent 4-amino-benzene-sulfonate (ABS) ligands. The two inter-chain Ag(I) atoms are bridged by two independent ABS ligands through weak Ag-O bonds and Ag⋯Ag attractions, forming a ladder-like chain coordination polymer [Ag(2)(ABS)(2)(bipy)(2)](n) parallel to [001], which is further linked to generate a two-dimensional structure via N-H⋯O hydrogen-bonding inter-actions.

No MeSH data available.


The molecular structure of the title compound, showing displacement ellipsoids at the 30% probability level; H-atoms have been excluded for clarity. The symmetry codes for the generated atoms: a (1 - x, -y, 1 - z), b (1 - x, -y, 2 - z), c (x, y, 1 + z), d (x, y, -1 + z), e (1 - x, -y, -z).
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Fap1: The molecular structure of the title compound, showing displacement ellipsoids at the 30% probability level; H-atoms have been excluded for clarity. The symmetry codes for the generated atoms: a (1 - x, -y, 1 - z), b (1 - x, -y, 2 - z), c (x, y, 1 + z), d (x, y, -1 + z), e (1 - x, -y, -z).


catena-Poly[[bis-(μ(2)-4-amino-benzene-sulfonato-κO:O)disilver]-bis-(μ(2)-4,4'-bipyridine-κN:N')].

Ou GC, Zhang M, Yuan XY, Dai YQ - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound, showing displacement ellipsoids at the 30% probability level; H-atoms have been excluded for clarity. The symmetry codes for the generated atoms: a (1 - x, -y, 1 - z), b (1 - x, -y, 2 - z), c (x, y, 1 + z), d (x, y, -1 + z), e (1 - x, -y, -z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960111&req=5

Fap1: The molecular structure of the title compound, showing displacement ellipsoids at the 30% probability level; H-atoms have been excluded for clarity. The symmetry codes for the generated atoms: a (1 - x, -y, 1 - z), b (1 - x, -y, 2 - z), c (x, y, 1 + z), d (x, y, -1 + z), e (1 - x, -y, -z).
Bottom Line: In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) and two O atoms from two independent 4-amino-benzene-sulfonate (ABS) ligands.The two inter-chain Ag(I) atoms are bridged by two independent ABS ligands through weak Ag-O bonds and Ag⋯Ag attractions, forming a ladder-like chain coordination polymer [Ag(2)(ABS)(2)(bipy)(2)](n) parallel to [001], which is further linked to generate a two-dimensional structure via N-H⋯O hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425100, People's Republic of China.

ABSTRACT
In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) and two O atoms from two independent 4-amino-benzene-sulfonate (ABS) ligands. The two inter-chain Ag(I) atoms are bridged by two independent ABS ligands through weak Ag-O bonds and Ag⋯Ag attractions, forming a ladder-like chain coordination polymer [Ag(2)(ABS)(2)(bipy)(2)](n) parallel to [001], which is further linked to generate a two-dimensional structure via N-H⋯O hydrogen-bonding inter-actions.

No MeSH data available.