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Dibromido(di-2-pyridylamine-κN,N')mercury(II).

Kalateh K, Norouzi A, Ebadi A, Ahmadi R, Amani V - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the mol-ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms.In the crystal structure, inter-molecular N-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers.There are π-π contacts between the pyridine rings [centroid-centroid distances = 3.9662 (5) and 3.9321 (4) Å].

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ABSTRACT
In the mol-ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms. In the crystal structure, inter-molecular N-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers. There are π-π contacts between the pyridine rings [centroid-centroid distances = 3.9662 (5) and 3.9321 (4) Å]. There also exists a C-H⋯π contact between the pyridine CH group and a pyridine ring.

No MeSH data available.


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A partial packing diagram of the title compound.
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Fap2: A partial packing diagram of the title compound.


Dibromido(di-2-pyridylamine-κN,N')mercury(II).

Kalateh K, Norouzi A, Ebadi A, Ahmadi R, Amani V - Acta Crystallogr Sect E Struct Rep Online (2008)

A partial packing diagram of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960074&req=5

Fap2: A partial packing diagram of the title compound.
Bottom Line: In the mol-ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms.In the crystal structure, inter-molecular N-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers.There are π-π contacts between the pyridine rings [centroid-centroid distances = 3.9662 (5) and 3.9321 (4) Å].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the mol-ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms. In the crystal structure, inter-molecular N-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers. There are π-π contacts between the pyridine rings [centroid-centroid distances = 3.9662 (5) and 3.9321 (4) Å]. There also exists a C-H⋯π contact between the pyridine CH group and a pyridine ring.

No MeSH data available.


Related in: MedlinePlus