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[1,1'-Bis(diphenyl-phosphino)ferrocene]carbon-yl[dihydro-bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate.

Huh S, Lough AJ - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand.The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand.In the crystal structure, there are weak inter-molecular C-H⋯O hydrogen bonds between complex mol-ecules and acetone solvent mol-ecules.

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ABSTRACT
In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa-hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1'-bis-(diphenyl-phosphino)ferrocene (dppf) ligand chelates with a larger bite angle of 101.90 (2)°, whereas the bite angle of the [H(2)Bpz(2)](-) ligand (pz = pyrazol-yl) is 85.67 (7)°. The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand. The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand. In the crystal structure, there are weak inter-molecular C-H⋯O hydrogen bonds between complex mol-ecules and acetone solvent mol-ecules.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound with 30% ellipsoids for non-hydrogen atoms. The solvent acetone molecule is not shown and H atoms bonded to C atoms have been omitted.
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Fap1: The molecular structure of the title compound with 30% ellipsoids for non-hydrogen atoms. The solvent acetone molecule is not shown and H atoms bonded to C atoms have been omitted.


[1,1'-Bis(diphenyl-phosphino)ferrocene]carbon-yl[dihydro-bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate.

Huh S, Lough AJ - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound with 30% ellipsoids for non-hydrogen atoms. The solvent acetone molecule is not shown and H atoms bonded to C atoms have been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960072&req=5

Fap1: The molecular structure of the title compound with 30% ellipsoids for non-hydrogen atoms. The solvent acetone molecule is not shown and H atoms bonded to C atoms have been omitted.
Bottom Line: The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand.The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand.In the crystal structure, there are weak inter-molecular C-H⋯O hydrogen bonds between complex mol-ecules and acetone solvent mol-ecules.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa-hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1'-bis-(diphenyl-phosphino)ferrocene (dppf) ligand chelates with a larger bite angle of 101.90 (2)°, whereas the bite angle of the [H(2)Bpz(2)](-) ligand (pz = pyrazol-yl) is 85.67 (7)°. The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand. The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand. In the crystal structure, there are weak inter-molecular C-H⋯O hydrogen bonds between complex mol-ecules and acetone solvent mol-ecules.

No MeSH data available.


Related in: MedlinePlus