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Bis[1,3-bis-(benzimidazol-2-yl)-2-oxapropane]copper(II)-picrate-dimethyl-formamide (1/2/4).

Yun R, Ying W, Qi B, Fan X, Wu H - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa-hedral environment by four N atoms and two O atoms forming two long Cu-O bonds.One of the unique dimethyl-formamide solvent mol-ecules is disordered over two sites with occupancies of 0.715 (6) and 0.285 (6).The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds.

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ABSTRACT
In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa-hedral environment by four N atoms and two O atoms forming two long Cu-O bonds. One of the unique dimethyl-formamide solvent mol-ecules is disordered over two sites with occupancies of 0.715 (6) and 0.285 (6). The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

The cation of the title compound showing displacement ellipsoids at the 30% probability level [symmetry code: (a) -x, -y+1, -x+1].
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Fap1: The cation of the title compound showing displacement ellipsoids at the 30% probability level [symmetry code: (a) -x, -y+1, -x+1].


Bis[1,3-bis-(benzimidazol-2-yl)-2-oxapropane]copper(II)-picrate-dimethyl-formamide (1/2/4).

Yun R, Ying W, Qi B, Fan X, Wu H - Acta Crystallogr Sect E Struct Rep Online (2008)

The cation of the title compound showing displacement ellipsoids at the 30% probability level [symmetry code: (a) -x, -y+1, -x+1].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960054&req=5

Fap1: The cation of the title compound showing displacement ellipsoids at the 30% probability level [symmetry code: (a) -x, -y+1, -x+1].
Bottom Line: In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa-hedral environment by four N atoms and two O atoms forming two long Cu-O bonds.One of the unique dimethyl-formamide solvent mol-ecules is disordered over two sites with occupancies of 0.715 (6) and 0.285 (6).The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa-hedral environment by four N atoms and two O atoms forming two long Cu-O bonds. One of the unique dimethyl-formamide solvent mol-ecules is disordered over two sites with occupancies of 0.715 (6) and 0.285 (6). The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus