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Poly[μ(2)-aqua-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole]bis-(μ(4)-naphthalene-1,4-dicarboxyl-ato)dimanganese(II)].

Chen ZQ, Zhang WZ, Xu Q - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral.The water mol-ecule and the L ligand are situated across a twofold rotation axis.The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, People's Republic of China.

ABSTRACT
In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral. The water mol-ecule and the L ligand are situated across a twofold rotation axis. The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network. O-H⋯O hydrogen bonds are observed within the network.

No MeSH data available.


Related in: MedlinePlus

Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.
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Fap1: Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.


Poly[μ(2)-aqua-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole]bis-(μ(4)-naphthalene-1,4-dicarboxyl-ato)dimanganese(II)].

Chen ZQ, Zhang WZ, Xu Q - Acta Crystallogr Sect E Struct Rep Online (2008)

Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960017&req=5

Fap1: Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.
Bottom Line: In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral.The water mol-ecule and the L ligand are situated across a twofold rotation axis.The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, People's Republic of China.

ABSTRACT
In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral. The water mol-ecule and the L ligand are situated across a twofold rotation axis. The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network. O-H⋯O hydrogen bonds are observed within the network.

No MeSH data available.


Related in: MedlinePlus