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Poly[μ(2)-aqua-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole]bis-(μ(4)-naphthalene-1,4-dicarboxyl-ato)dimanganese(II)].

Chen ZQ, Zhang WZ, Xu Q - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The water mol-ecule and the L ligand are situated across a twofold rotation axis.The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network.O-H⋯O hydrogen bonds are observed within the network.

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Affiliation: College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, People's Republic of China.

ABSTRACT
In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral. The water mol-ecule and the L ligand are situated across a twofold rotation axis. The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network. O-H⋯O hydrogen bonds are observed within the network.

No MeSH data available.


Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.
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Fap1: Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.


Poly[μ(2)-aqua-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole]bis-(μ(4)-naphthalene-1,4-dicarboxyl-ato)dimanganese(II)].

Chen ZQ, Zhang WZ, Xu Q - Acta Crystallogr Sect E Struct Rep Online (2008)

Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960017&req=5

Fap1: Part of the polymeric structure of the title compound, showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (i) 1-x, y, 3/2-z; (ii) 3/2-x, 1/2+y, 3/1-z; (iii) x-1/2, 1/2-y, z-1/2; (iv) -x, y, 1/2-z.
Bottom Line: The water mol-ecule and the L ligand are situated across a twofold rotation axis.The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network.O-H⋯O hydrogen bonds are observed within the network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, People's Republic of China.

ABSTRACT
In the title compound, [Mn(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n) or [Mn(2)(1,4-ndc)(2)(L)(H(2)O)](n), where 1,4-ndc is naphthalene-1,4-dicarboxyl-ate and L is 1,1'-(butane-1,4-di-yl)diimidazole, the coordination polyhedron around each Mn(II) atom is distorted octa-hedral. The water mol-ecule and the L ligand are situated across a twofold rotation axis. The Mn(II) atoms are bridged by 1,4-ndc and L ligands, forming a three-dimensional network. O-H⋯O hydrogen bonds are observed within the network.

No MeSH data available.