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catena-Poly[[(2,2'-bipyridine)copper(II)]-μ-5-tert-butyl-isophthalato].

Li XL, Huang ML - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl-isophthalate (tbip) and one 2,2'-bipyridine (bpy) ligand.The copper(II) ion is four-coordin-ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination.The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6).

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ABSTRACT
In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl-isophthalate (tbip) and one 2,2'-bipyridine (bpy) ligand. The copper(II) ion is four-coordin-ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6).

No MeSH data available.


A partial view, along the a axis, of the crystal packing of compound (I) showing the zigzag polymer chain. H atoms have been omitted for clarity.
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Fap2: A partial view, along the a axis, of the crystal packing of compound (I) showing the zigzag polymer chain. H atoms have been omitted for clarity.


catena-Poly[[(2,2'-bipyridine)copper(II)]-μ-5-tert-butyl-isophthalato].

Li XL, Huang ML - Acta Crystallogr Sect E Struct Rep Online (2008)

A partial view, along the a axis, of the crystal packing of compound (I) showing the zigzag polymer chain. H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2960003&req=5

Fap2: A partial view, along the a axis, of the crystal packing of compound (I) showing the zigzag polymer chain. H atoms have been omitted for clarity.
Bottom Line: In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl-isophthalate (tbip) and one 2,2'-bipyridine (bpy) ligand.The copper(II) ion is four-coordin-ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination.The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl-isophthalate (tbip) and one 2,2'-bipyridine (bpy) ligand. The copper(II) ion is four-coordin-ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6).

No MeSH data available.