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catena-Poly[[di-μ-chlorido-bis-{[6-methoxy-2-(4-methyl-phenyl-iminio-methyl)phenolato-κO,O']cadmium(II)}]-di-μ(2)-thio-cyanato-κN:S;κS:N].

Li HQ, Xian HD, Liu JF, Zhao GL - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methyl-phenyl-imino)meth-yl]-6-methoxy-phenol (HL) ligand, one thio-cyanate and one chloride ligand coordinated to a cadmium centre.The Cd(II) coordination environment contains two Cl atoms, one thio-cyanate (SCN) S atom, one isothio-cyanate (NCS) N atom and two O atoms from the HL ligand.The Schiff base ligand is in the trans conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methyl-phenyl-imino)meth-yl]-6-methoxy-phenol (HL) ligand, one thio-cyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thio-cyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thio-cyanate (SCN) S atom, one isothio-cyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation.

No MeSH data available.


The coordination around the cadmium(II) center, showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level.
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Fap1: The coordination around the cadmium(II) center, showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level.


catena-Poly[[di-μ-chlorido-bis-{[6-methoxy-2-(4-methyl-phenyl-iminio-methyl)phenolato-κO,O']cadmium(II)}]-di-μ(2)-thio-cyanato-κN:S;κS:N].

Li HQ, Xian HD, Liu JF, Zhao GL - Acta Crystallogr Sect E Struct Rep Online (2008)

The coordination around the cadmium(II) center, showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2959993&req=5

Fap1: The coordination around the cadmium(II) center, showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level.
Bottom Line: The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methyl-phenyl-imino)meth-yl]-6-methoxy-phenol (HL) ligand, one thio-cyanate and one chloride ligand coordinated to a cadmium centre.The Cd(II) coordination environment contains two Cl atoms, one thio-cyanate (SCN) S atom, one isothio-cyanate (NCS) N atom and two O atoms from the HL ligand.The Schiff base ligand is in the trans conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.

ABSTRACT
The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methyl-phenyl-imino)meth-yl]-6-methoxy-phenol (HL) ligand, one thio-cyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thio-cyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thio-cyanate (SCN) S atom, one isothio-cyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation.

No MeSH data available.