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Poly[4,4'-imino-dipyridinium [tetra-μ(3)-oxido-tetra-oxido-di-μ(4)-phosphato-κO:O':O'':O'''-tetra-vanadium(V)]].

Farnum GA, Laduca RL - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n-) layers.These aggregate into the three-dimensional structure via N-H⋯O hydrogen-bonding mechanisms imparted by 4,4'-imino-dipyridinium dications situated between the layers.

View Article: PubMed Central - HTML - PubMed

Affiliation: Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.

ABSTRACT
In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n-) layers. These aggregate into the three-dimensional structure via N-H⋯O hydrogen-bonding mechanisms imparted by 4,4'-imino-dipyridinium dications situated between the layers.

No MeSH data available.


Packing diagram illustrating the ABAB layer stacking pattern, which forms the 3-D crystal structure of (I) through hydrogen bonding between the inorganic layers and 4,4'-iminodipyridinium cations.
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Fap3: Packing diagram illustrating the ABAB layer stacking pattern, which forms the 3-D crystal structure of (I) through hydrogen bonding between the inorganic layers and 4,4'-iminodipyridinium cations.


Poly[4,4'-imino-dipyridinium [tetra-μ(3)-oxido-tetra-oxido-di-μ(4)-phosphato-κO:O':O'':O'''-tetra-vanadium(V)]].

Farnum GA, Laduca RL - Acta Crystallogr Sect E Struct Rep Online (2008)

Packing diagram illustrating the ABAB layer stacking pattern, which forms the 3-D crystal structure of (I) through hydrogen bonding between the inorganic layers and 4,4'-iminodipyridinium cations.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2959979&req=5

Fap3: Packing diagram illustrating the ABAB layer stacking pattern, which forms the 3-D crystal structure of (I) through hydrogen bonding between the inorganic layers and 4,4'-iminodipyridinium cations.
Bottom Line: In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n-) layers.These aggregate into the three-dimensional structure via N-H⋯O hydrogen-bonding mechanisms imparted by 4,4'-imino-dipyridinium dications situated between the layers.

View Article: PubMed Central - HTML - PubMed

Affiliation: Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.

ABSTRACT
In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n-) layers. These aggregate into the three-dimensional structure via N-H⋯O hydrogen-bonding mechanisms imparted by 4,4'-imino-dipyridinium dications situated between the layers.

No MeSH data available.