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Poly[[μ-1,4-anhydro-erythritolato-di-μ-aqua-sodium(I)] monohydrate].

Kerscher T, Zeller P, Mayer P, Klüfers P - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa-hedrally coordinated by two bridging 1,4-anhydro-erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands.This bonding pattern leads to one-dimensional anti-tactical polymeric chains along [010].One of the exocyclic O atoms of the anhydro-erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.

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Affiliation: Ludwig-Maximilians-Universität, Department Chemie, Butenandtstrasse 5-13, 81377 München, Germany.

ABSTRACT
In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa-hedrally coordinated by two bridging 1,4-anhydro-erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti-tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro-erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.

No MeSH data available.


The molecular structure of the title compound, with atom labels and anisotropic displacement ellipsoids (drawn at 50% probability level) for non-H atoms.
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Fap1: The molecular structure of the title compound, with atom labels and anisotropic displacement ellipsoids (drawn at 50% probability level) for non-H atoms.


Poly[[μ-1,4-anhydro-erythritolato-di-μ-aqua-sodium(I)] monohydrate].

Kerscher T, Zeller P, Mayer P, Klüfers P - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title compound, with atom labels and anisotropic displacement ellipsoids (drawn at 50% probability level) for non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2959930&req=5

Fap1: The molecular structure of the title compound, with atom labels and anisotropic displacement ellipsoids (drawn at 50% probability level) for non-H atoms.
Bottom Line: In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa-hedrally coordinated by two bridging 1,4-anhydro-erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands.This bonding pattern leads to one-dimensional anti-tactical polymeric chains along [010].One of the exocyclic O atoms of the anhydro-erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ludwig-Maximilians-Universität, Department Chemie, Butenandtstrasse 5-13, 81377 München, Germany.

ABSTRACT
In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa-hedrally coordinated by two bridging 1,4-anhydro-erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti-tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro-erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.

No MeSH data available.