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Dibromidobis(N,N-diethyl-dithio-carbamato-κS,S')tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate.

Zhang Q, Liu M - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The mol-ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu-μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core.Intramolecular O-H⋯S hydrogen bonds may stabilize the structure.Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China.

ABSTRACT
The mol-ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu-μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O-H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).

No MeSH data available.


The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
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Fap1: The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.


Dibromidobis(N,N-diethyl-dithio-carbamato-κS,S')tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate.

Zhang Q, Liu M - Acta Crystallogr Sect E Struct Rep Online (2008)

The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2959921&req=5

Fap1: The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
Bottom Line: The mol-ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu-μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core.Intramolecular O-H⋯S hydrogen bonds may stabilize the structure.Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China.

ABSTRACT
The mol-ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu-μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O-H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).

No MeSH data available.