Limits...
Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate.

Tabatabaee M, Aghabozorg H, Nasrolahzadeh R, Roshan L, Firoozi N - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd-O = 2.2399 (17)-2.2493 (17) Å] and two N atoms [Cd-N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxyl-ato ligands in a distorted octa-hedral geometry.The uncoordinated water mol-ecules are involved in O-H⋯O and N-H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supra-molecular structure, along with π-π stacking inter-actions [centroid-centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd-O = 2.2399 (17)-2.2493 (17) Å] and two N atoms [Cd-N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxyl-ato ligands in a distorted octa-hedral geometry. The uncoordinated water mol-ecules are involved in O-H⋯O and N-H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supra-molecular structure, along with π-π stacking inter-actions [centroid-centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions].

No MeSH data available.


Related in: MedlinePlus

A portion of the crystal structure of I showing the atomic numbering, hydrogen bonds (dashed lines) and 50% displacement ellipsoids [symmetry codes: (A) x - 1,y,z; (B) x - 1,y,z + 1; C) x,-y + 3/2,z + 3/2; (D) x,y,z + 1; (E) -x + 1,-y + 2,-z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2959406&req=5

Fap1: A portion of the crystal structure of I showing the atomic numbering, hydrogen bonds (dashed lines) and 50% displacement ellipsoids [symmetry codes: (A) x - 1,y,z; (B) x - 1,y,z + 1; C) x,-y + 3/2,z + 3/2; (D) x,y,z + 1; (E) -x + 1,-y + 2,-z].


Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate.

Tabatabaee M, Aghabozorg H, Nasrolahzadeh R, Roshan L, Firoozi N - Acta Crystallogr Sect E Struct Rep Online (2008)

A portion of the crystal structure of I showing the atomic numbering, hydrogen bonds (dashed lines) and 50% displacement ellipsoids [symmetry codes: (A) x - 1,y,z; (B) x - 1,y,z + 1; C) x,-y + 3/2,z + 3/2; (D) x,y,z + 1; (E) -x + 1,-y + 2,-z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2959406&req=5

Fap1: A portion of the crystal structure of I showing the atomic numbering, hydrogen bonds (dashed lines) and 50% displacement ellipsoids [symmetry codes: (A) x - 1,y,z; (B) x - 1,y,z + 1; C) x,-y + 3/2,z + 3/2; (D) x,y,z + 1; (E) -x + 1,-y + 2,-z].
Bottom Line: In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd-O = 2.2399 (17)-2.2493 (17) Å] and two N atoms [Cd-N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxyl-ato ligands in a distorted octa-hedral geometry.The uncoordinated water mol-ecules are involved in O-H⋯O and N-H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supra-molecular structure, along with π-π stacking inter-actions [centroid-centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd-O = 2.2399 (17)-2.2493 (17) Å] and two N atoms [Cd-N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxyl-ato ligands in a distorted octa-hedral geometry. The uncoordinated water mol-ecules are involved in O-H⋯O and N-H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supra-molecular structure, along with π-π stacking inter-actions [centroid-centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions].

No MeSH data available.


Related in: MedlinePlus