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(2S)-Ethyl 2-[(S(s))-benzyl-sulfinyl-amino]-3,3-dimethylbutanoate.

Zheng W, Sun X, Sun J, Wei BG - Acta Crystallogr Sect E Struct Rep Online (2008)

Bottom Line: The title compound, C(15)H(23)NO(3)S, is an unexpected 1,3-migration product in the addition of benzyl-zinc bromide to N-tert-butane-sulfinyl imino-acetate.In the crystal structure, mol-ecules are linked by N-H⋯O hydrogen bonds and weak C-H⋯O hydrogen bonds.

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ABSTRACT
The title compound, C(15)H(23)NO(3)S, is an unexpected 1,3-migration product in the addition of benzyl-zinc bromide to N-tert-butane-sulfinyl imino-acetate. In the crystal structure, mol-ecules are linked by N-H⋯O hydrogen bonds and weak C-H⋯O hydrogen bonds.

No MeSH data available.


Hydrogen bonding in the title compound. Symmetry code: (i) -x, y-1/2, -z+1.
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Fap2: Hydrogen bonding in the title compound. Symmetry code: (i) -x, y-1/2, -z+1.


(2S)-Ethyl 2-[(S(s))-benzyl-sulfinyl-amino]-3,3-dimethylbutanoate.

Zheng W, Sun X, Sun J, Wei BG - Acta Crystallogr Sect E Struct Rep Online (2008)

Hydrogen bonding in the title compound. Symmetry code: (i) -x, y-1/2, -z+1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2959368&req=5

Fap2: Hydrogen bonding in the title compound. Symmetry code: (i) -x, y-1/2, -z+1.
Bottom Line: The title compound, C(15)H(23)NO(3)S, is an unexpected 1,3-migration product in the addition of benzyl-zinc bromide to N-tert-butane-sulfinyl imino-acetate.In the crystal structure, mol-ecules are linked by N-H⋯O hydrogen bonds and weak C-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(15)H(23)NO(3)S, is an unexpected 1,3-migration product in the addition of benzyl-zinc bromide to N-tert-butane-sulfinyl imino-acetate. In the crystal structure, mol-ecules are linked by N-H⋯O hydrogen bonds and weak C-H⋯O hydrogen bonds.

No MeSH data available.