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Bis(2,4-dibromo-6-formyl-phenolato-κO,O')copper(II).

Li GZ, Zhang SH, Liu Z - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl-phenolate ligands in a slightly distorted square-planar coordination geometry.In the crystal structure, short inter-molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C-H⋯O hydrogen bonds generate a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Nonferrous Metal Materials and Processing Technology, Department of Materials and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin, 541004, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl-phenolate ligands in a slightly distorted square-planar coordination geometry. In the crystal structure, short inter-molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C-H⋯O hydrogen bonds generate a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

A view of (I), showing 30% probability displacement ellipsoids. Atoms labelled A are related to other atoms by the symmetry operation -x + 1, -y + 2, -z.
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Fap1: A view of (I), showing 30% probability displacement ellipsoids. Atoms labelled A are related to other atoms by the symmetry operation -x + 1, -y + 2, -z.


Bis(2,4-dibromo-6-formyl-phenolato-κO,O')copper(II).

Li GZ, Zhang SH, Liu Z - Acta Crystallogr Sect E Struct Rep Online (2007)

A view of (I), showing 30% probability displacement ellipsoids. Atoms labelled A are related to other atoms by the symmetry operation -x + 1, -y + 2, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914936&req=5

Fap1: A view of (I), showing 30% probability displacement ellipsoids. Atoms labelled A are related to other atoms by the symmetry operation -x + 1, -y + 2, -z.
Bottom Line: In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl-phenolate ligands in a slightly distorted square-planar coordination geometry.In the crystal structure, short inter-molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C-H⋯O hydrogen bonds generate a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Nonferrous Metal Materials and Processing Technology, Department of Materials and Chemical Engineering, Guilin University of Technology, Ministry of Education, Guilin, 541004, People's Republic of China.

ABSTRACT
In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl-phenolate ligands in a slightly distorted square-planar coordination geometry. In the crystal structure, short inter-molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C-H⋯O hydrogen bonds generate a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus