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Bis[N-(2-hydroxy-benzo-yl)pyridine-2-carboxamidrazonato-κN,N,O]manganese(II).

Li Y - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa-hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N(3)-salicyloylpyridine-2-carboxamidrazonato ligands.N-H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis.These two chains are cross-linked, building up layers parallel to the (100) plane.

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Affiliation: Department of Environmental Engineering, Anhui University of Technology, Maanshan 243002, People's Republic of China.

ABSTRACT
In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa-hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N(3)-salicyloylpyridine-2-carboxamidrazonato ligands. N-H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis. These two chains are cross-linked, building up layers parallel to the (100) plane.

No MeSH data available.


View down a, showing the crosslinking chains by hydrogen bonds. The c axis is horizontal. H atoms not involved in H bondings are removed for purpose of clarity.
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Fap2: View down a, showing the crosslinking chains by hydrogen bonds. The c axis is horizontal. H atoms not involved in H bondings are removed for purpose of clarity.


Bis[N-(2-hydroxy-benzo-yl)pyridine-2-carboxamidrazonato-κN,N,O]manganese(II).

Li Y - Acta Crystallogr Sect E Struct Rep Online (2007)

View down a, showing the crosslinking chains by hydrogen bonds. The c axis is horizontal. H atoms not involved in H bondings are removed for purpose of clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914934&req=5

Fap2: View down a, showing the crosslinking chains by hydrogen bonds. The c axis is horizontal. H atoms not involved in H bondings are removed for purpose of clarity.
Bottom Line: In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa-hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N(3)-salicyloylpyridine-2-carboxamidrazonato ligands.N-H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis.These two chains are cross-linked, building up layers parallel to the (100) plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Environmental Engineering, Anhui University of Technology, Maanshan 243002, People's Republic of China.

ABSTRACT
In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa-hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N(3)-salicyloylpyridine-2-carboxamidrazonato ligands. N-H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis. These two chains are cross-linked, building up layers parallel to the (100) plane.

No MeSH data available.