Limits...
Tetra-kis(N,N-diethyl-carbamato)titanium(IV).

Straessler NA, Caudle MT, Groy TL - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms.The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number.One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title compound with displacement ellipsoids shown at the 25% probability level. H atoms are omitted. Disorder of one ethyl group bonded to N1A is shown using C1D–C1E as the major component and C1D'–C1E' as the minor component.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2914932&req=5

Fap1: Molecular structure of the title compound with displacement ellipsoids shown at the 25% probability level. H atoms are omitted. Disorder of one ethyl group bonded to N1A is shown using C1D–C1E as the major component and C1D'–C1E' as the minor component.


Tetra-kis(N,N-diethyl-carbamato)titanium(IV).

Straessler NA, Caudle MT, Groy TL - Acta Crystallogr Sect E Struct Rep Online (2007)

Molecular structure of the title compound with displacement ellipsoids shown at the 25% probability level. H atoms are omitted. Disorder of one ethyl group bonded to N1A is shown using C1D–C1E as the major component and C1D'–C1E' as the minor component.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914932&req=5

Fap1: Molecular structure of the title compound with displacement ellipsoids shown at the 25% probability level. H atoms are omitted. Disorder of one ethyl group bonded to N1A is shown using C1D–C1E as the major component and C1D'–C1E' as the minor component.
Bottom Line: The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms.The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number.One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.

No MeSH data available.


Related in: MedlinePlus