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catena-Poly[[[aqua-manganese(II)]-di-μ-sulfato-[aqua-manganese(II)]-μ-N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine] hexa-hydrate].

Song AR, Hwang IC, Ha K - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: The repeat unit of the polymer, Mn(2)(SO(4))(2)(H(2)O)(2)(tphn), is disposed about a twofold axis passing through the centre of the dinuclear unit.The coordination geometry around the Mn centre is distorted octa-hedral.Two methylene groups are each disordered equally over two positions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the polymeric title compound, {[Mn(2)(SO(4))(2)(C(30)H(36)N(6))(H(2)O)(2)]·6H(2)O}(n), the two Mn(2+) ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexa-dentate ligand N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine (tphn), forming a one-dimensional chain structure running in the [101] direction. The repeat unit of the polymer, Mn(2)(SO(4))(2)(H(2)O)(2)(tphn), is disposed about a twofold axis passing through the centre of the dinuclear unit. The coordination geometry around the Mn centre is distorted octa-hedral. Two methylene groups are each disordered equally over two positions.

No MeSH data available.


View of the unit-cell contents and chain structure of the title compound. H atoms at C atoms have been omitted for clarity. Hydrogen-bond interactions are drawn with dashed lines.
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Fap2: View of the unit-cell contents and chain structure of the title compound. H atoms at C atoms have been omitted for clarity. Hydrogen-bond interactions are drawn with dashed lines.


catena-Poly[[[aqua-manganese(II)]-di-μ-sulfato-[aqua-manganese(II)]-μ-N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine] hexa-hydrate].

Song AR, Hwang IC, Ha K - Acta Crystallogr Sect E Struct Rep Online (2007)

View of the unit-cell contents and chain structure of the title compound. H atoms at C atoms have been omitted for clarity. Hydrogen-bond interactions are drawn with dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914929&req=5

Fap2: View of the unit-cell contents and chain structure of the title compound. H atoms at C atoms have been omitted for clarity. Hydrogen-bond interactions are drawn with dashed lines.
Bottom Line: The repeat unit of the polymer, Mn(2)(SO(4))(2)(H(2)O)(2)(tphn), is disposed about a twofold axis passing through the centre of the dinuclear unit.The coordination geometry around the Mn centre is distorted octa-hedral.Two methylene groups are each disordered equally over two positions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the polymeric title compound, {[Mn(2)(SO(4))(2)(C(30)H(36)N(6))(H(2)O)(2)]·6H(2)O}(n), the two Mn(2+) ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexa-dentate ligand N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine (tphn), forming a one-dimensional chain structure running in the [101] direction. The repeat unit of the polymer, Mn(2)(SO(4))(2)(H(2)O)(2)(tphn), is disposed about a twofold axis passing through the centre of the dinuclear unit. The coordination geometry around the Mn centre is distorted octa-hedral. Two methylene groups are each disordered equally over two positions.

No MeSH data available.