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Aqua-bis(3,5-dimethyl-1H-pyrazole-κN)(oxalato-κO,O')copper(II).

Buvailo AI, Tomyn SV, Haukka M, Pavlenko VA, Fritsky IO - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: In the title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)(H(2)O)], the Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by two N atoms belonging to the two 3,5-dimethyl-1H-pyrazole ligands, two O atoms of the oxalate anion providing an O,O'-chelating coordination mode, and an O atom of the water mol-ecule occupying the apical position.The crystal packing shows a well defined layer structure.Intra-layer connections are realised through a system of hydrogen bonds while the nature of the inter-layer inter-actions is completely hydro-phobic, including no hydrogen-bonding inter-actions.

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ABSTRACT
In the title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)(H(2)O)], the Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by two N atoms belonging to the two 3,5-dimethyl-1H-pyrazole ligands, two O atoms of the oxalate anion providing an O,O'-chelating coordination mode, and an O atom of the water mol-ecule occupying the apical position. The crystal packing shows a well defined layer structure. Intra-layer connections are realised through a system of hydrogen bonds while the nature of the inter-layer inter-actions is completely hydro-phobic, including no hydrogen-bonding inter-actions.

No MeSH data available.


A packing diagram for the title compound, showing the layers along the c-axis direction. Hydrogen bonds are indicated by dashed lines. H atoms not included in hydrogen bonds are omitted for clarity.
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Fap2: A packing diagram for the title compound, showing the layers along the c-axis direction. Hydrogen bonds are indicated by dashed lines. H atoms not included in hydrogen bonds are omitted for clarity.


Aqua-bis(3,5-dimethyl-1H-pyrazole-κN)(oxalato-κO,O')copper(II).

Buvailo AI, Tomyn SV, Haukka M, Pavlenko VA, Fritsky IO - Acta Crystallogr Sect E Struct Rep Online (2007)

A packing diagram for the title compound, showing the layers along the c-axis direction. Hydrogen bonds are indicated by dashed lines. H atoms not included in hydrogen bonds are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914925&req=5

Fap2: A packing diagram for the title compound, showing the layers along the c-axis direction. Hydrogen bonds are indicated by dashed lines. H atoms not included in hydrogen bonds are omitted for clarity.
Bottom Line: In the title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)(H(2)O)], the Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by two N atoms belonging to the two 3,5-dimethyl-1H-pyrazole ligands, two O atoms of the oxalate anion providing an O,O'-chelating coordination mode, and an O atom of the water mol-ecule occupying the apical position.The crystal packing shows a well defined layer structure.Intra-layer connections are realised through a system of hydrogen bonds while the nature of the inter-layer inter-actions is completely hydro-phobic, including no hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cu(C(2)O(4))(C(5)H(8)N(2))(2)(H(2)O)], the Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by two N atoms belonging to the two 3,5-dimethyl-1H-pyrazole ligands, two O atoms of the oxalate anion providing an O,O'-chelating coordination mode, and an O atom of the water mol-ecule occupying the apical position. The crystal packing shows a well defined layer structure. Intra-layer connections are realised through a system of hydrogen bonds while the nature of the inter-layer inter-actions is completely hydro-phobic, including no hydrogen-bonding inter-actions.

No MeSH data available.