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(Azido-κN)[6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolato-κN,N',O]copper(II).

Sun X - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolate Schiff base ligand and one azide ligand.The mol-ecules are connected by a combination of two π-π inter-actions [centroid-centroid distances 3.359 (3) and 3.378 (2) Å] and one C-H⋯N hydrogen bond into a two-dimensional supra-molecular network structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Technology, Shandong University, Jinan 250100, People's Republic of China .

ABSTRACT
The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolate Schiff base ligand and one azide ligand. The mol-ecules are connected by a combination of two π-π inter-actions [centroid-centroid distances 3.359 (3) and 3.378 (2) Å] and one C-H⋯N hydrogen bond into a two-dimensional supra-molecular network structure.

No MeSH data available.


Related in: MedlinePlus

A stereoview of part of the crystal structure of (I), showing the two-dimensional supramolecular structure. For the sake of clarity, H atoms bonded to C atoms and not involved in the motif shown have been omitted. Atoms marked with an asterisk (*), a hash (#) or a dollar sign ($) are at the symmetry positions (-x + 2, -y, -z + 1), (-x + 1, -y, -z + 1), (x, y + 1, z) and (x, y + 1, z), respectively.
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Fap2: A stereoview of part of the crystal structure of (I), showing the two-dimensional supramolecular structure. For the sake of clarity, H atoms bonded to C atoms and not involved in the motif shown have been omitted. Atoms marked with an asterisk (*), a hash (#) or a dollar sign ($) are at the symmetry positions (-x + 2, -y, -z + 1), (-x + 1, -y, -z + 1), (x, y + 1, z) and (x, y + 1, z), respectively.


(Azido-κN)[6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolato-κN,N',O]copper(II).

Sun X - Acta Crystallogr Sect E Struct Rep Online (2007)

A stereoview of part of the crystal structure of (I), showing the two-dimensional supramolecular structure. For the sake of clarity, H atoms bonded to C atoms and not involved in the motif shown have been omitted. Atoms marked with an asterisk (*), a hash (#) or a dollar sign ($) are at the symmetry positions (-x + 2, -y, -z + 1), (-x + 1, -y, -z + 1), (x, y + 1, z) and (x, y + 1, z), respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914922&req=5

Fap2: A stereoview of part of the crystal structure of (I), showing the two-dimensional supramolecular structure. For the sake of clarity, H atoms bonded to C atoms and not involved in the motif shown have been omitted. Atoms marked with an asterisk (*), a hash (#) or a dollar sign ($) are at the symmetry positions (-x + 2, -y, -z + 1), (-x + 1, -y, -z + 1), (x, y + 1, z) and (x, y + 1, z), respectively.
Bottom Line: The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolate Schiff base ligand and one azide ligand.The mol-ecules are connected by a combination of two π-π inter-actions [centroid-centroid distances 3.359 (3) and 3.378 (2) Å] and one C-H⋯N hydrogen bond into a two-dimensional supra-molecular network structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemistry and Chemical Technology, Shandong University, Jinan 250100, People's Republic of China .

ABSTRACT
The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolate Schiff base ligand and one azide ligand. The mol-ecules are connected by a combination of two π-π inter-actions [centroid-centroid distances 3.359 (3) and 3.378 (2) Å] and one C-H⋯N hydrogen bond into a two-dimensional supra-molecular network structure.

No MeSH data available.


Related in: MedlinePlus