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Poly[[aqua-(1-naphthyl-acetato)cadmium(II)]-μ(3)-pyridin-3-olato].

Ma CY, Song WD, Xi DL - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: In the title complex, [Cd(C(5)H(4)NO)(C(12)H(9)O(2))(H(2)O)](n), each Cd(II) atom is coordinated by two carboxylate O atoms from one 1-naphthyl-acetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water mol-ecule, and displays a distorted octa-hedral coordination geometry.The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthyl-acetate-Cd(II) units parallel to the b axis, with a Cd⋯Cd separation of 3.578 (2) Å.The chains are further self-assembled into a supra-molecular network through inter-molecular O-H⋯O hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Environmental Science and Engineering, Dong Hua University, Shanghai 200051, People's Republic of China.

ABSTRACT
In the title complex, [Cd(C(5)H(4)NO)(C(12)H(9)O(2))(H(2)O)](n), each Cd(II) atom is coordinated by two carboxylate O atoms from one 1-naphthyl-acetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water mol-ecule, and displays a distorted octa-hedral coordination geometry. The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthyl-acetate-Cd(II) units parallel to the b axis, with a Cd⋯Cd separation of 3.578 (2) Å. The chains are further self-assembled into a supra-molecular network through inter-molecular O-H⋯O hydrogen-bonding inter-actions.

No MeSH data available.


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The structure of the title compound, showing the atomic numbering scheme. Non-H atoms are shown with 30% probability displacement ellipsoids. Unlabeled atoms are related to the labelled atoms by the symmetry operator (1 - x, 2 - y, 1 - z).
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Fap1: The structure of the title compound, showing the atomic numbering scheme. Non-H atoms are shown with 30% probability displacement ellipsoids. Unlabeled atoms are related to the labelled atoms by the symmetry operator (1 - x, 2 - y, 1 - z).


Poly[[aqua-(1-naphthyl-acetato)cadmium(II)]-μ(3)-pyridin-3-olato].

Ma CY, Song WD, Xi DL - Acta Crystallogr Sect E Struct Rep Online (2007)

The structure of the title compound, showing the atomic numbering scheme. Non-H atoms are shown with 30% probability displacement ellipsoids. Unlabeled atoms are related to the labelled atoms by the symmetry operator (1 - x, 2 - y, 1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914920&req=5

Fap1: The structure of the title compound, showing the atomic numbering scheme. Non-H atoms are shown with 30% probability displacement ellipsoids. Unlabeled atoms are related to the labelled atoms by the symmetry operator (1 - x, 2 - y, 1 - z).
Bottom Line: In the title complex, [Cd(C(5)H(4)NO)(C(12)H(9)O(2))(H(2)O)](n), each Cd(II) atom is coordinated by two carboxylate O atoms from one 1-naphthyl-acetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water mol-ecule, and displays a distorted octa-hedral coordination geometry.The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthyl-acetate-Cd(II) units parallel to the b axis, with a Cd⋯Cd separation of 3.578 (2) Å.The chains are further self-assembled into a supra-molecular network through inter-molecular O-H⋯O hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Environmental Science and Engineering, Dong Hua University, Shanghai 200051, People's Republic of China.

ABSTRACT
In the title complex, [Cd(C(5)H(4)NO)(C(12)H(9)O(2))(H(2)O)](n), each Cd(II) atom is coordinated by two carboxylate O atoms from one 1-naphthyl-acetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water mol-ecule, and displays a distorted octa-hedral coordination geometry. The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthyl-acetate-Cd(II) units parallel to the b axis, with a Cd⋯Cd separation of 3.578 (2) Å. The chains are further self-assembled into a supra-molecular network through inter-molecular O-H⋯O hydrogen-bonding inter-actions.

No MeSH data available.


Related in: MedlinePlus